Crystallographic order and decomposition of [MnIII6CrIII]3+ single-molecule magnets deposited in submonolayers and monolayers on HOPG studied by means of molecular resolved Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy in UHV

Gryzia A, Volkmann T, Brechling A, Hoeke V, Schneider L, Küpper K, Glaser T, Heinzmann U (2014)
Nanoscale Research Letters 9(1): 60.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
Monolayers and submonolayers of [MnIII6CrIII]3+ single-molecule magnets (SMMs) adsorbed on highly oriented pyrolytic graphite (HOPG) using the droplet technique characterized by non-contact atomic force microscopy (nc-AFM) as well as by Kelvin probe force microscopy (KPFM) show island-like structures with heights resembling the height of the molecule. Furthermore, islands were found which revealed ordered 1D as well as 2D structures with periods close to the width of the SMMs. Along this, islands which show half the heights of intact SMMs were observed which are evidences for a decomposing process of the molecules during the preparation. Finally, models for the structure of the ordered SMM adsorbates are proposed to explain the observations.
Stichworte
Ordered monolayer; KPFM; AFM; Single-molecule magnet; UHV; HOPG; Decomposition
Erscheinungsjahr
2014
Zeitschriftentitel
Nanoscale Research Letters
Band
9
Ausgabe
1
Art.-Nr.
60
ISSN
1931-7573
eISSN
1556-276X
Finanzierungs-Informationen
Open-Access-Publikationskosten wurden durch die Deutsche Forschungsgemeinschaft und die Universität Bielefeld gefördert.
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https://pub.uni-bielefeld.de/record/2651935

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Gryzia A, Volkmann T, Brechling A, et al. Crystallographic order and decomposition of [MnIII6CrIII]3+ single-molecule magnets deposited in submonolayers and monolayers on HOPG studied by means of molecular resolved Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy in UHV. Nanoscale Research Letters. 2014;9(1): 60.
Gryzia, A., Volkmann, T., Brechling, A., Hoeke, V., Schneider, L., Küpper, K., Glaser, T., et al. (2014). Crystallographic order and decomposition of [MnIII6CrIII]3+ single-molecule magnets deposited in submonolayers and monolayers on HOPG studied by means of molecular resolved Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy in UHV. Nanoscale Research Letters, 9(1), 60. doi:10.1186/1556-276X-9-60
Gryzia, Aaron, Volkmann, Timm, Brechling, Armin, Hoeke, Veronika, Schneider, Lilli, Küpper, Karsten, Glaser, Thorsten, and Heinzmann, Ulrich. 2014. “Crystallographic order and decomposition of [MnIII6CrIII]3+ single-molecule magnets deposited in submonolayers and monolayers on HOPG studied by means of molecular resolved Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy in UHV”. Nanoscale Research Letters 9 (1): 60.
Gryzia, A., Volkmann, T., Brechling, A., Hoeke, V., Schneider, L., Küpper, K., Glaser, T., and Heinzmann, U. (2014). Crystallographic order and decomposition of [MnIII6CrIII]3+ single-molecule magnets deposited in submonolayers and monolayers on HOPG studied by means of molecular resolved Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy in UHV. Nanoscale Research Letters 9:60.
Gryzia, A., et al., 2014. Crystallographic order and decomposition of [MnIII6CrIII]3+ single-molecule magnets deposited in submonolayers and monolayers on HOPG studied by means of molecular resolved Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy in UHV. Nanoscale Research Letters, 9(1): 60.
A. Gryzia, et al., “Crystallographic order and decomposition of [MnIII6CrIII]3+ single-molecule magnets deposited in submonolayers and monolayers on HOPG studied by means of molecular resolved Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy in UHV”, Nanoscale Research Letters, vol. 9, 2014, : 60.
Gryzia, A., Volkmann, T., Brechling, A., Hoeke, V., Schneider, L., Küpper, K., Glaser, T., Heinzmann, U.: Crystallographic order and decomposition of [MnIII6CrIII]3+ single-molecule magnets deposited in submonolayers and monolayers on HOPG studied by means of molecular resolved Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy in UHV. Nanoscale Research Letters. 9, : 60 (2014).
Gryzia, Aaron, Volkmann, Timm, Brechling, Armin, Hoeke, Veronika, Schneider, Lilli, Küpper, Karsten, Glaser, Thorsten, and Heinzmann, Ulrich. “Crystallographic order and decomposition of [MnIII6CrIII]3+ single-molecule magnets deposited in submonolayers and monolayers on HOPG studied by means of molecular resolved Atomic Force Microscopy (AFM) and Kelvin Probe Force Microscopy in UHV”. Nanoscale Research Letters 9.1 (2014): 60.
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