Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes
Feldscher B, Theil H, Stammler A, Bögge H, Glaser T (2012)
Inorganic Chemistry 51(16): 8652-8654.
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Einrichtung
Abstract / Bemerkung
An unprecedented trinucleating ligand with a central 1,3,5-trimercaptobenzene unit and its trinuclear Cu-3(II) complex are presented. The high covalency of the difficult-to-realize Cu-II-SR bond provides an order of magnitude increase in the superexchange interaction in comparison to its oxygen analogue.
Erscheinungsjahr
2012
Zeitschriftentitel
Inorganic Chemistry
Band
51
Ausgabe
16
Seite(n)
8652-8654
ISSN
0020-1669
eISSN
1520-510X
Page URI
https://pub.uni-bielefeld.de/record/2544286
Zitieren
Feldscher B, Theil H, Stammler A, Bögge H, Glaser T. Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry. 2012;51(16):8652-8654.
Feldscher, B., Theil, H., Stammler, A., Bögge, H., & Glaser, T. (2012). Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry, 51(16), 8652-8654. doi:10.1021/ic301312v
Feldscher, Bastian, Theil, Hubert, Stammler, Anja, Bögge, Hartmut, and Glaser, Thorsten. 2012. “Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes”. Inorganic Chemistry 51 (16): 8652-8654.
Feldscher, B., Theil, H., Stammler, A., Bögge, H., and Glaser, T. (2012). Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry 51, 8652-8654.
Feldscher, B., et al., 2012. Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry, 51(16), p 8652-8654.
B. Feldscher, et al., “Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes”, Inorganic Chemistry, vol. 51, 2012, pp. 8652-8654.
Feldscher, B., Theil, H., Stammler, A., Bögge, H., Glaser, T.: Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry. 51, 8652-8654 (2012).
Feldscher, Bastian, Theil, Hubert, Stammler, Anja, Bögge, Hartmut, and Glaser, Thorsten. “Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes”. Inorganic Chemistry 51.16 (2012): 8652-8654.
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3 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
A streamlined synthesis of extended thiophloroglucinol ligands and their trinuclear NiII3 complexes.
Feldscher B, Theil H, Stammler A, Bögge H, Glaser T., Dalton Trans 43(10), 2014
PMID: 24457995
Feldscher B, Theil H, Stammler A, Bögge H, Glaser T., Dalton Trans 43(10), 2014
PMID: 24457995
Aromatic versus heteroradialene character in extended thiophloroglucinol ligands and their trinuclear nickel(II) complexes.
Feldscher B, Stammler A, Bögge H, Glaser T., Chem Asian J 9(8), 2014
PMID: 24976372
Feldscher B, Stammler A, Bögge H, Glaser T., Chem Asian J 9(8), 2014
PMID: 24976372
Switching from antiferromagnetic to ferromagnetic coupling in heptanuclear [M(t)6M(c)](n+) complexes by going from an achiral to a chiral triplesalen ligand.
Mukherjee C, Hoeke V, Stammler A, Bögge H, Schnack J, Glaser T., Dalton Trans 43(25), 2014
PMID: 24835147
Mukherjee C, Hoeke V, Stammler A, Bögge H, Schnack J, Glaser T., Dalton Trans 43(25), 2014
PMID: 24835147
References
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Teil dieser Dissertation
Synthese von modifizierten Phloroglucin- und Thiophloroglucinliganden : gezielte Optimierung von Einzelmolekülmagneten
Feldscher B (2012)
Bielefeld.
Feldscher B (2012)
Bielefeld.
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