Synthesis and structural characterization of a monofunctionalized phloroglucin-derivative: A precursor for heterotrinuclear meta-phenylene bridged complexes
Glaser T, Heidemeier M, Krickemeyer E, Bögge H (2006)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 61(6): 753-757.
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Einrichtung
Abstract / Bemerkung
As part of our synthetic efforts for new triplesalen derivatives, we reacted 2,4,6-triacetyl-1,3,5-trihydroxybenzene (1) with excess Cu(ClO4)(2) center dot 6H(2)O, imidazole, and ethylenediamine. However, not the triple ketimine derivative was formed but the mononuclear Cull complex [LCuII(ImH)jClO(4) center dot 0.5EtOH center dot 0.5H(2)O (HL = 6-(1-(2-aminoethylimino)ethyl)-2,4-diacetyl-1,3,5-trihydroxybenzene) with only one ketimine function. This complex forms a one-dimensional coordination polymer in the solid state through the apical binding of a keto-oxygen atom of one cation to the Cu-II ion of a neighboring cation. Magnetic measurements reveal the presence of weak antiferromagnetic intra-chain interactions.
Stichworte
N ligands;
magnetic properties;
Cu complexes
Erscheinungsjahr
2006
Zeitschriftentitel
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Band
61
Ausgabe
6
Seite(n)
753-757
ISSN
0932-0776
Page URI
https://pub.uni-bielefeld.de/record/1598313
Zitieren
Glaser T, Heidemeier M, Krickemeyer E, Bögge H. Synthesis and structural characterization of a monofunctionalized phloroglucin-derivative: A precursor for heterotrinuclear meta-phenylene bridged complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2006;61(6):753-757.
Glaser, T., Heidemeier, M., Krickemeyer, E., & Bögge, H. (2006). Synthesis and structural characterization of a monofunctionalized phloroglucin-derivative: A precursor for heterotrinuclear meta-phenylene bridged complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 61(6), 753-757.
Glaser, Thorsten, Heidemeier, Maik, Krickemeyer, Erich, and Bögge, Hartmut. 2006. “Synthesis and structural characterization of a monofunctionalized phloroglucin-derivative: A precursor for heterotrinuclear meta-phenylene bridged complexes”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 61 (6): 753-757.
Glaser, T., Heidemeier, M., Krickemeyer, E., and Bögge, H. (2006). Synthesis and structural characterization of a monofunctionalized phloroglucin-derivative: A precursor for heterotrinuclear meta-phenylene bridged complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 61, 753-757.
Glaser, T., et al., 2006. Synthesis and structural characterization of a monofunctionalized phloroglucin-derivative: A precursor for heterotrinuclear meta-phenylene bridged complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 61(6), p 753-757.
T. Glaser, et al., “Synthesis and structural characterization of a monofunctionalized phloroglucin-derivative: A precursor for heterotrinuclear meta-phenylene bridged complexes”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 61, 2006, pp. 753-757.
Glaser, T., Heidemeier, M., Krickemeyer, E., Bögge, H.: Synthesis and structural characterization of a monofunctionalized phloroglucin-derivative: A precursor for heterotrinuclear meta-phenylene bridged complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 61, 753-757 (2006).
Glaser, Thorsten, Heidemeier, Maik, Krickemeyer, Erich, and Bögge, Hartmut. “Synthesis and structural characterization of a monofunctionalized phloroglucin-derivative: A precursor for heterotrinuclear meta-phenylene bridged complexes”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 61.6 (2006): 753-757.
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