Chlorodefluorination Induced by Gallium-Based Lewis Acids
Tölke K, Neumann B, Stammler H-G, Hoge B (2024)
Chemistry - A European Journal .
Zeitschriftenaufsatz
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Einrichtung
Abstract / Bemerkung
The reaction of [Ga(C2F5)3(FSiMe3)] with chlorotrimethylsilane leads to the selective substitution of thealpha-fluorine atoms by chlorine atoms and thus to the formation of [Ga(CCl2CF3)3(FSiMe3)]. The corresponding chlorogallate ion, [Ga(CCl2CF3)3Cl]-, could be isolated and structurally characterized as its tetraphenylphosphonium salt. The catalytic potential of [Ga(CCl2CF3)3(FSiMe3)] was demonstrated via the chlorodefluorination of Me3SiCF3, 2,2-difluoropropane and [PPh4][Ga(C2F5)4]. © 2024 Wiley‐VCH GmbH.
Erscheinungsjahr
2024
Zeitschriftentitel
Chemistry - A European Journal
eISSN
1521-3765
Page URI
https://pub.uni-bielefeld.de/record/2992787
Zitieren
Tölke K, Neumann B, Stammler H-G, Hoge B. Chlorodefluorination Induced by Gallium-Based Lewis Acids. Chemistry - A European Journal . 2024.
Tölke, K., Neumann, B., Stammler, H. - G., & Hoge, B. (2024). Chlorodefluorination Induced by Gallium-Based Lewis Acids. Chemistry - A European Journal . https://doi.org/10.1002/chem.202403226
Tölke, Katharina, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. 2024. “Chlorodefluorination Induced by Gallium-Based Lewis Acids”. Chemistry - A European Journal .
Tölke, K., Neumann, B., Stammler, H. - G., and Hoge, B. (2024). Chlorodefluorination Induced by Gallium-Based Lewis Acids. Chemistry - A European Journal .
Tölke, K., et al., 2024. Chlorodefluorination Induced by Gallium-Based Lewis Acids. Chemistry - A European Journal .
K. Tölke, et al., “Chlorodefluorination Induced by Gallium-Based Lewis Acids”, Chemistry - A European Journal , 2024.
Tölke, K., Neumann, B., Stammler, H.-G., Hoge, B.: Chlorodefluorination Induced by Gallium-Based Lewis Acids. Chemistry - A European Journal . (2024).
Tölke, Katharina, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Chlorodefluorination Induced by Gallium-Based Lewis Acids”. Chemistry - A European Journal (2024).
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