Optimizing SnO Quantum Dot Precursor Solutions for Perovskite Solar Cells with Reduced Hysteresis

Sannino GV, Gries TW, Wang Q, Caso MF, De Maria A, Lancellotti L, Mercaldo LV, Muñoz-García AB, Pavone M, Abate A, Veneri PD (2024)
Solar RRL.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Sannino, Gennaro V.; Gries, Thomas W.; Wang, Qiong; Caso, Maria Federica; De Maria, Antonella; Lancellotti, Laura; Mercaldo, Lucia V.; Muñoz-García, Ana Belén; Pavone, Michele; Abate, AntonioUniBi ; Veneri, Paola Delli
Abstract / Bemerkung
In recent years, SnO2quantum dots (QDs) have been widely used for preparing the electron transport layer (ETL) within perovskite solar cells (PSCs). However, the fabricated devices exhibit an evident hysteresis unless interlayer materials are introduced to passivate or prevent the formation of trap states at the SnO2‐perovskite interface. Herein, we propose the use of the zwitterion 3‐(1‐pyridinio)‐1‐propanesulfonate (PPS) as additive inside the SnO2quantum dots solution. Our results highlight that the PPS plays a multifunctional role by accelerating the synthesis of the QDs, enhancing the electron transfer and passivating defects at the SnO2‐perovskite interface. The resulting PSCs with SnO2QDs incorporating PPS exhibit a remarkable reduction in hysteresis index (HI) compared to those prepared with thiourea or without any additives. This reduction in HI suggests that PPS serves as a cost‐effective alternative additive for SnO2QDs preparation, eliminating the need for additional interlayers or expensive additives. This article is protected by copyright. All rights reserved.
Erscheinungsjahr
2024
Zeitschriftentitel
Solar RRL
ISSN
2367-198X
eISSN
2367-198X
Page URI
https://pub.uni-bielefeld.de/record/2986973

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Sannino GV, Gries TW, Wang Q, et al. Optimizing SnO Quantum Dot Precursor Solutions for Perovskite Solar Cells with Reduced Hysteresis. Solar RRL. 2024.
Sannino, G. V., Gries, T. W., Wang, Q., Caso, M. F., De Maria, A., Lancellotti, L., Mercaldo, L. V., et al. (2024). Optimizing SnO Quantum Dot Precursor Solutions for Perovskite Solar Cells with Reduced Hysteresis. Solar RRL. https://doi.org/10.1002/solr.202300977
Sannino, Gennaro V., Gries, Thomas W., Wang, Qiong, Caso, Maria Federica, De Maria, Antonella, Lancellotti, Laura, Mercaldo, Lucia V., et al. 2024. “Optimizing SnO Quantum Dot Precursor Solutions for Perovskite Solar Cells with Reduced Hysteresis”. Solar RRL.
Sannino, G. V., Gries, T. W., Wang, Q., Caso, M. F., De Maria, A., Lancellotti, L., Mercaldo, L. V., Muñoz-García, A. B., Pavone, M., Abate, A., et al. (2024). Optimizing SnO Quantum Dot Precursor Solutions for Perovskite Solar Cells with Reduced Hysteresis. Solar RRL.
Sannino, G.V., et al., 2024. Optimizing SnO Quantum Dot Precursor Solutions for Perovskite Solar Cells with Reduced Hysteresis. Solar RRL.
G.V. Sannino, et al., “Optimizing SnO Quantum Dot Precursor Solutions for Perovskite Solar Cells with Reduced Hysteresis”, Solar RRL, 2024.
Sannino, G.V., Gries, T.W., Wang, Q., Caso, M.F., De Maria, A., Lancellotti, L., Mercaldo, L.V., Muñoz-García, A.B., Pavone, M., Abate, A., Veneri, P.D.: Optimizing SnO Quantum Dot Precursor Solutions for Perovskite Solar Cells with Reduced Hysteresis. Solar RRL. (2024).
Sannino, Gennaro V., Gries, Thomas W., Wang, Qiong, Caso, Maria Federica, De Maria, Antonella, Lancellotti, Laura, Mercaldo, Lucia V., Muñoz-García, Ana Belén, Pavone, Michele, Abate, Antonio, and Veneri, Paola Delli. “Optimizing SnO Quantum Dot Precursor Solutions for Perovskite Solar Cells with Reduced Hysteresis”. Solar RRL (2024).
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