Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake

Ebeler, Falk; Vishnevskiy, Yury; Neumann, Beate; Stammler, Hans-Georg; Ghadwal, Rajendra

Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake

Ebeler F, Vishnevskiy Y, Neumann B, Stammler H-G, Ghadwal R (2024)
Advanced Science 11(5).

Zeitschriftenaufsatz | Veröffentlicht | Englisch

Download

2023 - Ebeler et al. - Isolation of an Anionic Dicarbene Embedded Sn2P2 Cluster and Reversible CO2 Uptake.pdf 1.80 MB

DOI

https://doi.org/10.1002/advs.202305545

URN

urn:nbn:de:0070-pub-29848083

Autor*in

Ebeler, Falk; Vishnevskiy, Yury^UniBi; Neumann, Beate^UniBi; Stammler, Hans-Georg^UniBi; Ghadwal, Rajendra^UniBi

Einrichtung

Fakultät für Chemie > Anorganische Chemie und Strukturchemie

Abstract / Bemerkung

Decarbonylation of a cyclic bis‐phosphaethynolatostannylene [(ADC)Sn(PCO)]₂based on an anionic dicarbene framework (ADC = PhC{N(Dipp)C}₂; Dipp = 2,6‐iPr₂C₆H₃) under UV light results in the formation of a Sn₂P₂cluster compound [(ADC)SnP]₂as a green crystalline solid. The electronic structure of [(ADC)SnP]₂is analyzed by quantum‐chemical calculations. At room temperature, [(ADC)SnP]₂reversibly binds with CO₂and forms [(ADC)₂{SnOC(O)P}SnP]. [(ADC)SnP]₂enables catalytic hydroboration of CO₂and reacts with elemental selenium and Fe₂(CO)₉to afford [(ADC)₂{Sn(Se)P₂}SnSe] and [(ADC)Sn{Fe(CO)₄}P]₂, respectively. All compounds are characterized by multinuclear NMR spectroscopy and their solid‐state molecular structures are determined by single‐crystal X‐ray diffraction.

Erscheinungsjahr

2024

Zeitschriftentitel

Advanced Science

Band

Ausgabe

Urheberrecht / Lizenzen

Creative Commons Namensnennung 4.0 International Public License (CC-BY 4.0)

ISSN

2198-3844

eISSN

2198-3844

Finanzierungs-Informationen

Open-Access-Publikationskosten wurden durch die Universität Bielefeld gefördert.

Page URI

https://pub.uni-bielefeld.de/record/2984808

Zitieren

Ebeler F, Vishnevskiy Y, Neumann B, Stammler H-G, Ghadwal R. Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake. Advanced Science. 2024;11(5).

Ebeler, F., Vishnevskiy, Y., Neumann, B., Stammler, H. - G., & Ghadwal, R. (2024). Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake. Advanced Science, 11(5). https://doi.org/10.1002/advs.202305545

Ebeler, Falk, Vishnevskiy, Yury, Neumann, Beate, Stammler, Hans-Georg, and Ghadwal, Rajendra. 2024. “Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake”. Advanced Science 11 (5).

Ebeler, F., Vishnevskiy, Y., Neumann, B., Stammler, H. - G., and Ghadwal, R. (2024). Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake. Advanced Science 11.

Ebeler, F., et al., 2024. Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake. Advanced Science, 11(5).

F. Ebeler, et al., “Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake”, Advanced Science, vol. 11, 2024.

Ebeler, F., Vishnevskiy, Y., Neumann, B., Stammler, H.-G., Ghadwal, R.: Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake. Advanced Science. 11, (2024).

Ebeler, Falk, Vishnevskiy, Yury, Neumann, Beate, Stammler, Hans-Georg, and Ghadwal, Rajendra. “Isolation of an Anionic Dicarbene Embedded Sn 2 P 2 Cluster and Reversible CO 2 Uptake”. Advanced Science 11.5 (2024).

Alle Dateien verfügbar unter der/den folgenden Lizenz(en):

Creative Commons Namensnennung 4.0 International Public License (CC-BY 4.0):