Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups
Hajdin I, Pajkert R, Keßler M, Han J, Mei H, Röschenthaler G-V (2023)
Beilstein Journal of Organic Chemistry 19: 541-549.
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Autor*in
Hajdin, Ita;
Pajkert, Romana;
Keßler, MiraUniBi;
Han, Jianlin;
Mei, Haibo;
Röschenthaler, Gerd-Volker
Einrichtung
Abstract / Bemerkung
A synthetic route to the bench-stable fluorinated masked carbene reagent diethyl 2-diazo-1,1,3,3,3-pentafluoropropylphosphonate, bearing a trifluoromethyl and a difluoromethyl group is reported for the first time. Its application in CuI-catalyzed cyclopropanation reactions with aromatic and aliphatic terminal alkenes under mild reaction conditions is demonstrated. In total, sixteen new cyclopropanes were synthesized in good to very good yields. Copyright © 2023, Hajdin et al.
Erscheinungsjahr
2023
Zeitschriftentitel
Beilstein Journal of Organic Chemistry
Band
19
Seite(n)
541-549
eISSN
1860-5397
Page URI
https://pub.uni-bielefeld.de/record/2979167
Zitieren
Hajdin I, Pajkert R, Keßler M, Han J, Mei H, Röschenthaler G-V. Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups. Beilstein Journal of Organic Chemistry . 2023;19:541-549.
Hajdin, I., Pajkert, R., Keßler, M., Han, J., Mei, H., & Röschenthaler, G. - V. (2023). Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups. Beilstein Journal of Organic Chemistry , 19, 541-549. https://doi.org/10.3762/bjoc.19.39
Hajdin, Ita, Pajkert, Romana, Keßler, Mira, Han, Jianlin, Mei, Haibo, and Röschenthaler, Gerd-Volker. 2023. “Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups”. Beilstein Journal of Organic Chemistry 19: 541-549.
Hajdin, I., Pajkert, R., Keßler, M., Han, J., Mei, H., and Röschenthaler, G. - V. (2023). Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups. Beilstein Journal of Organic Chemistry 19, 541-549.
Hajdin, I., et al., 2023. Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups. Beilstein Journal of Organic Chemistry , 19, p 541-549.
I. Hajdin, et al., “Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups”, Beilstein Journal of Organic Chemistry , vol. 19, 2023, pp. 541-549.
Hajdin, I., Pajkert, R., Keßler, M., Han, J., Mei, H., Röschenthaler, G.-V.: Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups. Beilstein Journal of Organic Chemistry . 19, 541-549 (2023).
Hajdin, Ita, Pajkert, Romana, Keßler, Mira, Han, Jianlin, Mei, Haibo, and Röschenthaler, Gerd-Volker. “Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups”. Beilstein Journal of Organic Chemistry 19 (2023): 541-549.
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