pi-Extension of the Tribenzotriquinacene Framework: Efficient Vinylene and Arylene Bay Bridging Based on a New C3-Symmetric Key Derivative
Wang H-Z, Hung T-Y, Ip H-W, Lee M-K, Sun X-Q, Kuck D, Chow H-F (2023)
Chemistry - A European Journal 29(36): e202300793.
Zeitschriftenaufsatz
| E-Veröff. vor dem Druck | Englisch
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Autor*in
Wang, Huai-Zhen;
Hung, Tsz-Yu;
Ip, Ho-Wang;
Lee, Man-Kit;
Sun, Xiao-Qing;
Kuck, DietmarUniBi;
Chow, Hak-Fun
Abstract / Bemerkung
1,5,9-Tribromo-2,3,6,7,10,11-hexamethoxy-4b1-methyltribenzo-triquinacene, a C3-symmetric TBTQ derivative, can be prepared conveniently and with high regioselectivity from readily available starting materials. It is a versatile key compound for the synthesis of other chiral 1,5,9-trifunctionalized TBTQ derivatives and pi-extended congeners in which the bays of the TBTQ skeleton are bridged by vinylene units and 1,2-arylene units. X-ray crystal structure analysis and UV-vis spectroscopy show that vinylene bay-bridging enables better pi-conjugation with the arene rings of the TBTQ core than 1,2-arylene bay-bridging does. © 2023 Wiley-VCH GmbH.
Erscheinungsjahr
2023
Zeitschriftentitel
Chemistry - A European Journal
Band
29
Ausgabe
36
Art.-Nr.
e202300793
Urheberrecht / Lizenzen
eISSN
1521-3765
Page URI
https://pub.uni-bielefeld.de/record/2978084
Zitieren
Wang H-Z, Hung T-Y, Ip H-W, et al. pi-Extension of the Tribenzotriquinacene Framework: Efficient Vinylene and Arylene Bay Bridging Based on a New C3-Symmetric Key Derivative. Chemistry - A European Journal. 2023;29(36): e202300793.
Wang, H. - Z., Hung, T. - Y., Ip, H. - W., Lee, M. - K., Sun, X. - Q., Kuck, D., & Chow, H. - F. (2023). pi-Extension of the Tribenzotriquinacene Framework: Efficient Vinylene and Arylene Bay Bridging Based on a New C3-Symmetric Key Derivative. Chemistry - A European Journal, 29(36), e202300793. https://doi.org/10.1002/chem.202300793
Wang, Huai-Zhen, Hung, Tsz-Yu, Ip, Ho-Wang, Lee, Man-Kit, Sun, Xiao-Qing, Kuck, Dietmar, and Chow, Hak-Fun. 2023. “pi-Extension of the Tribenzotriquinacene Framework: Efficient Vinylene and Arylene Bay Bridging Based on a New C3-Symmetric Key Derivative”. Chemistry - A European Journal 29 (36): e202300793.
Wang, H. - Z., Hung, T. - Y., Ip, H. - W., Lee, M. - K., Sun, X. - Q., Kuck, D., and Chow, H. - F. (2023). pi-Extension of the Tribenzotriquinacene Framework: Efficient Vinylene and Arylene Bay Bridging Based on a New C3-Symmetric Key Derivative. Chemistry - A European Journal 29:e202300793.
Wang, H.-Z., et al., 2023. pi-Extension of the Tribenzotriquinacene Framework: Efficient Vinylene and Arylene Bay Bridging Based on a New C3-Symmetric Key Derivative. Chemistry - A European Journal, 29(36): e202300793.
H.-Z. Wang, et al., “pi-Extension of the Tribenzotriquinacene Framework: Efficient Vinylene and Arylene Bay Bridging Based on a New C3-Symmetric Key Derivative”, Chemistry - A European Journal, vol. 29, 2023, : e202300793.
Wang, H.-Z., Hung, T.-Y., Ip, H.-W., Lee, M.-K., Sun, X.-Q., Kuck, D., Chow, H.-F.: pi-Extension of the Tribenzotriquinacene Framework: Efficient Vinylene and Arylene Bay Bridging Based on a New C3-Symmetric Key Derivative. Chemistry - A European Journal. 29, : e202300793 (2023).
Wang, Huai-Zhen, Hung, Tsz-Yu, Ip, Ho-Wang, Lee, Man-Kit, Sun, Xiao-Qing, Kuck, Dietmar, and Chow, Hak-Fun. “pi-Extension of the Tribenzotriquinacene Framework: Efficient Vinylene and Arylene Bay Bridging Based on a New C3-Symmetric Key Derivative”. Chemistry - A European Journal 29.36 (2023): e202300793.
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