Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts
Porath S, Keßler M, Neumann B, Stammler H-G, Hoge B (2023)
Chemistry - A European Journal 29(20): 7.
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In the rising field of organoindium chemistry little is known about the perfluoroorganyl-substituted indium compounds. The increasing use of indium reagents is explained by their high stability and tolerance towards water and functional groups. Here we report on the synthesis of the novel tetrakis(pentafluoroethyl)indate, [In(C2F5)4]-, and its characterization in salts with the cations [Li(thf)3]+, Cs+, [PPh4]+and [H14O6]2+(thf = tetrahydrofuran). To the best of our knowledge, these salts constitute the first perfluoroalkylindates and, in general, the first isolated perfluoroalkylindium compounds which are fully characterized by NMR spectroscopy, mass spectrometry, elemental analysis and X-ray diffraction analysis. © 2023 Wiley-VCH GmbH.
Erscheinungsjahr
2023
Zeitschriftentitel
Chemistry - A European Journal
Band
29
Ausgabe
20
Seite(n)
7
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eISSN
1521-3765
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Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.
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https://pub.uni-bielefeld.de/record/2968371
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Porath S, Keßler M, Neumann B, Stammler H-G, Hoge B. Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts. Chemistry - A European Journal . 2023;29(20):7.
Porath, S., Keßler, M., Neumann, B., Stammler, H. - G., & Hoge, B. (2023). Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts. Chemistry - A European Journal , 29(20), 7. https://doi.org/10.1002/chem.202203278
Porath, Sven, Keßler, Mira, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. 2023. “Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts”. Chemistry - A European Journal 29 (20): 7.
Porath, S., Keßler, M., Neumann, B., Stammler, H. - G., and Hoge, B. (2023). Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts. Chemistry - A European Journal 29, 7.
Porath, S., et al., 2023. Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts. Chemistry - A European Journal , 29(20), p 7.
S. Porath, et al., “Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts”, Chemistry - A European Journal , vol. 29, 2023, pp. 7.
Porath, S., Keßler, M., Neumann, B., Stammler, H.-G., Hoge, B.: Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts. Chemistry - A European Journal . 29, 7 (2023).
Porath, Sven, Keßler, Mira, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts”. Chemistry - A European Journal 29.20 (2023): 7.
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2024-01-23T09:29:46Z
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Dissertation, die diesen PUB Eintrag enthält
Perfluoroorganyl Gallium and Indium Compounds. Synthesis, Properties and Reaktivity
Porath S (2022)
Bielefeld: Universität Bielefeld.
Porath S (2022)
Bielefeld: Universität Bielefeld.
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