Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr11M2} complexes

Alotaibi R, Brookfield A, Fowler JM, Whitehead GFS, Lockyer SJ, Timco GA, Collison D, Schnack J, Winpenny REP (2022)
Dalton Transactions.

Zeitschriftenaufsatz | E-Veröff. vor dem Druck | Englisch
 
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Autor*in
Alotaibi, Rajeh; Brookfield, Adam; Fowler, Jonathan M; Whitehead, George F S; Lockyer, Selena J; Timco, Grigore A; Collison, David; Schnack, JürgenUniBi ; Winpenny, Richard E P
Abstract / Bemerkung
Addition of 1,4,8,11-tetrazacyclotetradecane (cyclam) to a reaction that produces octametallic rings when simpler amines are used, produces {Cr11M2} "pretzels" (M = ZnII or CuII) where the cyclam coordinates to the MII ion which then sits at the centre of a twelve-metal macrocycle. Magnetic studies were fitted using the finite-temperature Lanczos method (FTLM), and the results demonstrate that exchange interactions are transferable from previous exchange-coupled CrIII rings.
Erscheinungsjahr
2022
Zeitschriftentitel
Dalton Transactions
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/2967678

Zitieren

Alotaibi R, Brookfield A, Fowler JM, et al. Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr11M2} complexes. Dalton Transactions. 2022.
Alotaibi, R., Brookfield, A., Fowler, J. M., Whitehead, G. F. S., Lockyer, S. J., Timco, G. A., Collison, D., et al. (2022). Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr11M2} complexes. Dalton Transactions. https://doi.org/10.1039/d2dt03368b
Alotaibi, Rajeh, Brookfield, Adam, Fowler, Jonathan M, Whitehead, George F S, Lockyer, Selena J, Timco, Grigore A, Collison, David, Schnack, Jürgen, and Winpenny, Richard E P. 2022. “Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr11M2} complexes”. Dalton Transactions.
Alotaibi, R., Brookfield, A., Fowler, J. M., Whitehead, G. F. S., Lockyer, S. J., Timco, G. A., Collison, D., Schnack, J., and Winpenny, R. E. P. (2022). Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr11M2} complexes. Dalton Transactions.
Alotaibi, R., et al., 2022. Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr11M2} complexes. Dalton Transactions.
R. Alotaibi, et al., “Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr11M2} complexes”, Dalton Transactions, 2022.
Alotaibi, R., Brookfield, A., Fowler, J.M., Whitehead, G.F.S., Lockyer, S.J., Timco, G.A., Collison, D., Schnack, J., Winpenny, R.E.P.: Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr11M2} complexes. Dalton Transactions. (2022).
Alotaibi, Rajeh, Brookfield, Adam, Fowler, Jonathan M, Whitehead, George F S, Lockyer, Selena J, Timco, Grigore A, Collison, David, Schnack, Jürgen, and Winpenny, Richard E P. “Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {Cr11M2} complexes”. Dalton Transactions (2022).
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