Borane promoted aryl transfer reaction for the synthesis of alpha-aryl functionalised beta-hydroxy and beta-keto esters

Kaehler T, Lorenz J, Ould DMC, Engl D, Santi M, Gierlichs L, Wirth T, Melen RL (2022)
Organic and Biomolecular Chemistry .

Zeitschriftenaufsatz | E-Veröff. vor dem Druck | Englisch
 
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Autor*in
Kaehler, Tanja; Lorenz, Jonas; Ould, Darren M. C.; Engl, Dorothea; Santi, MicolUniBi; Gierlichs, Lukas; Wirth, Thomas; Melen, Rebecca L.
Abstract / Bemerkung
The synthesis of a series of alpha-aryl or alpha-alkyl functionalised beta-hydroxy and beta-keto esters has been achieved by reacting alpha-diazoesters with boranes, and aldehydes, ketones, anhydrides, nitriles, esters or isocyanates. In a mild reaction protocol, 26 examples are presented in yields up to 73%.
Erscheinungsjahr
2022
Zeitschriftentitel
Organic and Biomolecular Chemistry
ISSN
1477-0520
eISSN
1477-0539
Page URI
https://pub.uni-bielefeld.de/record/2963474

Zitieren

Kaehler T, Lorenz J, Ould DMC, et al. Borane promoted aryl transfer reaction for the synthesis of alpha-aryl functionalised beta-hydroxy and beta-keto esters. Organic and Biomolecular Chemistry . 2022.
Kaehler, T., Lorenz, J., Ould, D. M. C., Engl, D., Santi, M., Gierlichs, L., Wirth, T., et al. (2022). Borane promoted aryl transfer reaction for the synthesis of alpha-aryl functionalised beta-hydroxy and beta-keto esters. Organic and Biomolecular Chemistry . https://doi.org/10.1039/d2ob00643j
Kaehler, T., Lorenz, J., Ould, D. M. C., Engl, D., Santi, M., Gierlichs, L., Wirth, T., and Melen, R. L. (2022). Borane promoted aryl transfer reaction for the synthesis of alpha-aryl functionalised beta-hydroxy and beta-keto esters. Organic and Biomolecular Chemistry .
Kaehler, T., et al., 2022. Borane promoted aryl transfer reaction for the synthesis of alpha-aryl functionalised beta-hydroxy and beta-keto esters. Organic and Biomolecular Chemistry .
T. Kaehler, et al., “Borane promoted aryl transfer reaction for the synthesis of alpha-aryl functionalised beta-hydroxy and beta-keto esters”, Organic and Biomolecular Chemistry , 2022.
Kaehler, T., Lorenz, J., Ould, D.M.C., Engl, D., Santi, M., Gierlichs, L., Wirth, T., Melen, R.L.: Borane promoted aryl transfer reaction for the synthesis of alpha-aryl functionalised beta-hydroxy and beta-keto esters. Organic and Biomolecular Chemistry . (2022).
Kaehler, Tanja, Lorenz, Jonas, Ould, Darren M. C., Engl, Dorothea, Santi, Micol, Gierlichs, Lukas, Wirth, Thomas, and Melen, Rebecca L. “Borane promoted aryl transfer reaction for the synthesis of alpha-aryl functionalised beta-hydroxy and beta-keto esters”. Organic and Biomolecular Chemistry (2022).

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