Diphenyl- and Dimesityl-Phosphanyl-Substituted 3,3,4,4,5,5-Hexafluorocyclopentenyl-Gold(I) Dimers - Syntheses and Solid-State Structures
Müller F, Neumann B, Stammler H-G, Mitzel NW (2022)
European Journal of Inorganic Chemistry 2022(14): e202200080.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Autor*in
Abstract / Bemerkung
1,2-Dichloro-3,3,4,4,5,5-hexafluorocyclopentene (F(6)cypCl(2)) was functionalized with diphenyl- and dimesitylphosphanyl groups by a salt-elimination reaction of the respective chlorophosphane (PPh2Cl, PMes(2)Cl) with in situ generated lithiated F(6)cyp(Li)Cl. F(6)cyp(PR2)Cl (R=Ph, Mes) was functionalised again to obtain the corresponding trimethylstannyl substituted compounds F(6)cyp(PR2)(SnMe3) (R=Ph, Mes). These tin-precursors were used in tin-gold exchange reactions to synthesize the dinuclear gold(I) dimers [F(6)cyp(PR2)Au](2) (R=Ph, Mes). For the mesityl substituted compound, the phosphanegold chloride adduct F(6)cyp(PMes(2)AuCl)(SnMe3), the intermediate of the tin-gold exchange reaction, could also be isolated. All compounds were characterized by multinuclear NMR spectroscopy and X-ray diffraction experiments.
Stichworte
Aurophilicity;
Crystal engineering;
Gold;
Steric effects;
Tin-gold;
exchange
Erscheinungsjahr
2022
Zeitschriftentitel
European Journal of Inorganic Chemistry
Band
2022
Ausgabe
14
Art.-Nr.
e202200080
Urheberrecht / Lizenzen
ISSN
1434-1948
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/2962438
Zitieren
Müller F, Neumann B, Stammler H-G, Mitzel NW. Diphenyl- and Dimesityl-Phosphanyl-Substituted 3,3,4,4,5,5-Hexafluorocyclopentenyl-Gold(I) Dimers - Syntheses and Solid-State Structures. European Journal of Inorganic Chemistry . 2022;2022(14): e202200080.
Müller, F., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2022). Diphenyl- and Dimesityl-Phosphanyl-Substituted 3,3,4,4,5,5-Hexafluorocyclopentenyl-Gold(I) Dimers - Syntheses and Solid-State Structures. European Journal of Inorganic Chemistry , 2022(14), e202200080. https://doi.org/10.1002/ejic.202200080
Müller, Felix, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. 2022. “Diphenyl- and Dimesityl-Phosphanyl-Substituted 3,3,4,4,5,5-Hexafluorocyclopentenyl-Gold(I) Dimers - Syntheses and Solid-State Structures”. European Journal of Inorganic Chemistry 2022 (14): e202200080.
Müller, F., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2022). Diphenyl- and Dimesityl-Phosphanyl-Substituted 3,3,4,4,5,5-Hexafluorocyclopentenyl-Gold(I) Dimers - Syntheses and Solid-State Structures. European Journal of Inorganic Chemistry 2022:e202200080.
Müller, F., et al., 2022. Diphenyl- and Dimesityl-Phosphanyl-Substituted 3,3,4,4,5,5-Hexafluorocyclopentenyl-Gold(I) Dimers - Syntheses and Solid-State Structures. European Journal of Inorganic Chemistry , 2022(14): e202200080.
F. Müller, et al., “Diphenyl- and Dimesityl-Phosphanyl-Substituted 3,3,4,4,5,5-Hexafluorocyclopentenyl-Gold(I) Dimers - Syntheses and Solid-State Structures”, European Journal of Inorganic Chemistry , vol. 2022, 2022, : e202200080.
Müller, F., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Diphenyl- and Dimesityl-Phosphanyl-Substituted 3,3,4,4,5,5-Hexafluorocyclopentenyl-Gold(I) Dimers - Syntheses and Solid-State Structures. European Journal of Inorganic Chemistry . 2022, : e202200080 (2022).
Müller, Felix, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Diphenyl- and Dimesityl-Phosphanyl-Substituted 3,3,4,4,5,5-Hexafluorocyclopentenyl-Gold(I) Dimers - Syntheses and Solid-State Structures”. European Journal of Inorganic Chemistry 2022.14 (2022): e202200080.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Creative Commons Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International (CC BY-NC-ND 4.0):
Volltext(e)
Access Level
Open Access
Zuletzt Hochgeladen
2022-07-06T16:32:59Z
MD5 Prüfsumme
21e7de552c14beef4410d639317ca4b7
Link(s) zu Volltext(en)
Access Level
Open Access
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Suchen in
Google Scholar