Aggregation of Copper(I) and Silver(I) Chloride Phosphane Complexes Determined by Aryl-Stacking and Weak Hydrogen Bonds in the Ligand Periphery
Müller F, Mix A, Stammler H-G, Mitzel NW (2022)
European Journal of Inorganic Chemistry: e202101083.
Zeitschriftenaufsatz
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Abstract / Bemerkung
Starting from pentafluorobenzene and 1,2,3,4-tetrafluorobenzene, the phosphane ligands (o-C6F4R)Me2P (R=H, F), as well as their copper(I) and silver(I) chloride complexes [(o-C6F4R)Me2P](2)MCl (M=Cu, Ag; R=H, F) were synthesized. All complexes were characterized by multinuclear NMR spectroscopy and CHN analyses. Their solid-state structures were determined by X-ray diffraction experiments and compared with each other with regard to their aggregation motifs. The aggregation in solution was investigated by variable-temperature diffusion-ordered NMR spectroscopy (VT-DOSY) experiments.
Stichworte
Aryl-aryl stacking;
Copper;
Crystal engineering;
Silver;
Structure;
elucidation
Erscheinungsjahr
2022
Zeitschriftentitel
European Journal of Inorganic Chemistry
Art.-Nr.
e202101083
ISSN
1434-1948
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/2962191
Zitieren
Müller F, Mix A, Stammler H-G, Mitzel NW. Aggregation of Copper(I) and Silver(I) Chloride Phosphane Complexes Determined by Aryl-Stacking and Weak Hydrogen Bonds in the Ligand Periphery. European Journal of Inorganic Chemistry. 2022: e202101083.
Müller, F., Mix, A., Stammler, H. - G., & Mitzel, N. W. (2022). Aggregation of Copper(I) and Silver(I) Chloride Phosphane Complexes Determined by Aryl-Stacking and Weak Hydrogen Bonds in the Ligand Periphery. European Journal of Inorganic Chemistry, e202101083. https://doi.org/10.1002/ejic.202101083
Müller, Felix, Mix, Andreas, Stammler, Hans-Georg, and Mitzel, Norbert W. 2022. “Aggregation of Copper(I) and Silver(I) Chloride Phosphane Complexes Determined by Aryl-Stacking and Weak Hydrogen Bonds in the Ligand Periphery”. European Journal of Inorganic Chemistry: e202101083.
Müller, F., Mix, A., Stammler, H. - G., and Mitzel, N. W. (2022). Aggregation of Copper(I) and Silver(I) Chloride Phosphane Complexes Determined by Aryl-Stacking and Weak Hydrogen Bonds in the Ligand Periphery. European Journal of Inorganic Chemistry:e202101083.
Müller, F., et al., 2022. Aggregation of Copper(I) and Silver(I) Chloride Phosphane Complexes Determined by Aryl-Stacking and Weak Hydrogen Bonds in the Ligand Periphery. European Journal of Inorganic Chemistry, : e202101083.
F. Müller, et al., “Aggregation of Copper(I) and Silver(I) Chloride Phosphane Complexes Determined by Aryl-Stacking and Weak Hydrogen Bonds in the Ligand Periphery”, European Journal of Inorganic Chemistry, 2022, : e202101083.
Müller, F., Mix, A., Stammler, H.-G., Mitzel, N.W.: Aggregation of Copper(I) and Silver(I) Chloride Phosphane Complexes Determined by Aryl-Stacking and Weak Hydrogen Bonds in the Ligand Periphery. European Journal of Inorganic Chemistry. : e202101083 (2022).
Müller, Felix, Mix, Andreas, Stammler, Hans-Georg, and Mitzel, Norbert W. “Aggregation of Copper(I) and Silver(I) Chloride Phosphane Complexes Determined by Aryl-Stacking and Weak Hydrogen Bonds in the Ligand Periphery”. European Journal of Inorganic Chemistry (2022): e202101083.
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