Advances and recent trends in dipnictenes chemistry
Weber L, Ebeler F, Ghadwal R (2022)
Coordination Chemistry Reviews 461: 214499.
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Abstract / Bemerkung
Dipnictenes are molecules comprising a double bond between two Group 15 elements (referred as pnictogens (Pn) = P, As, Sb, Bi). Over the last decades, the chemistry of dipnictenes has undergone a remarkable advance. This is largely because of the advancement of new ligand sets with distinct stereoelectronic properties. In general, classical dipnictenes are kinetically stabilized by the use of extremely bulky aryl or alkyl substituents. In recent years, numerous ligand frameworks featuring non-carbon donor substituents have also been introduced in dipnictenes chemistry. Now a plethora of dipnictenes with divergent electronic structure, reactivity, and physical properties are known. Among carbon-donor substituents, stable N-heterocyclic carbenes (NHCs) and other singlet carbenes have also been used as potent Lewis bases to derive related unsaturated species. A comprehensive understanding of the structure, bonding, and reactivity of a whole series of dipnictenes (RPn=PnR) (R = a substituent) as well as the influence of substituents on the nature of these species will be instrumental for the advancement of the field, in particular to unveil the relevance of these molecules in materials science. The aim of this review is to outline recent advances in dipnictene chemistry with a special focus on their reactivity. The outcomes show that dipnictenes have emerged from simple laboratory curiosities to versatile and useful synthons in modern main-group chemistry, which is expected to evolve further.
Erscheinungsjahr
2022
Zeitschriftentitel
Coordination Chemistry Reviews
Band
461
Art.-Nr.
214499
ISSN
0010-8545
Page URI
https://pub.uni-bielefeld.de/record/2962090
Zitieren
Weber L, Ebeler F, Ghadwal R. Advances and recent trends in dipnictenes chemistry. Coordination Chemistry Reviews. 2022;461: 214499.
Weber, L., Ebeler, F., & Ghadwal, R. (2022). Advances and recent trends in dipnictenes chemistry. Coordination Chemistry Reviews, 461, 214499. https://doi.org/10.1016/j.ccr.2022.214499
Weber, Lothar, Ebeler, Falk, and Ghadwal, Rajendra. 2022. “Advances and recent trends in dipnictenes chemistry”. Coordination Chemistry Reviews 461: 214499.
Weber, L., Ebeler, F., and Ghadwal, R. (2022). Advances and recent trends in dipnictenes chemistry. Coordination Chemistry Reviews 461:214499.
Weber, L., Ebeler, F., & Ghadwal, R., 2022. Advances and recent trends in dipnictenes chemistry. Coordination Chemistry Reviews, 461: 214499.
L. Weber, F. Ebeler, and R. Ghadwal, “Advances and recent trends in dipnictenes chemistry”, Coordination Chemistry Reviews, vol. 461, 2022, : 214499.
Weber, L., Ebeler, F., Ghadwal, R.: Advances and recent trends in dipnictenes chemistry. Coordination Chemistry Reviews. 461, : 214499 (2022).
Weber, Lothar, Ebeler, Falk, and Ghadwal, Rajendra. “Advances and recent trends in dipnictenes chemistry”. Coordination Chemistry Reviews 461 (2022): 214499.
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