Synthesis of Bifunctional Boron-Lewis Acids - Thorough Investigation of the Adduct Formation with Pyrimidine

Rudlof J, Glodde T, Mix A, Neumann B, Stammler H-G, Mitzel NW (2022)
European Journal of Inorganic Chemistry : e202100842.

Zeitschriftenaufsatz | E-Veröff. vor dem Druck | Englisch
 
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Abstract / Bemerkung
Three bifunctional boron-Lewis acids based on a 1,2-diethynylbenzene backbone were synthesized using a tin-boron exchange protocol in good to very good yields. Complexation experiments with pyrimidine were thoroughly investigated using the example of 1,2-bis(benzo[d][1,3,2]dioxaborol-2-ylethynyl)benzene (3) in solution, in the solid phase and by quantum-chemical calculations. Two adducts were structurally investigated by X-ray diffraction experiments. DOSY-/VT-NMR experiments gave insight into the dynamic behaviour of the synthesized poly-Lewis acids with pyrimidine.
Stichworte
Adduct formation; Boron; Poly-Lewis acids; Structure elucidation; Tin
Erscheinungsjahr
2022
Zeitschriftentitel
European Journal of Inorganic Chemistry
Art.-Nr.
e202100842
ISSN
1434-1948
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/2960715

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Rudlof J, Glodde T, Mix A, Neumann B, Stammler H-G, Mitzel NW. Synthesis of Bifunctional Boron-Lewis Acids - Thorough Investigation of the Adduct Formation with Pyrimidine. European Journal of Inorganic Chemistry . 2022: e202100842.
Rudlof, J., Glodde, T., Mix, A., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2022). Synthesis of Bifunctional Boron-Lewis Acids - Thorough Investigation of the Adduct Formation with Pyrimidine. European Journal of Inorganic Chemistry , e202100842. https://doi.org/10.1002/ejic.202100842
Rudlof, J., Glodde, T., Mix, A., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2022). Synthesis of Bifunctional Boron-Lewis Acids - Thorough Investigation of the Adduct Formation with Pyrimidine. European Journal of Inorganic Chemistry :e202100842.
Rudlof, J., et al., 2022. Synthesis of Bifunctional Boron-Lewis Acids - Thorough Investigation of the Adduct Formation with Pyrimidine. European Journal of Inorganic Chemistry , : e202100842.
J. Rudlof, et al., “Synthesis of Bifunctional Boron-Lewis Acids - Thorough Investigation of the Adduct Formation with Pyrimidine”, European Journal of Inorganic Chemistry , 2022, : e202100842.
Rudlof, J., Glodde, T., Mix, A., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Synthesis of Bifunctional Boron-Lewis Acids - Thorough Investigation of the Adduct Formation with Pyrimidine. European Journal of Inorganic Chemistry . : e202100842 (2022).
Rudlof, Jens, Glodde, Timo, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Synthesis of Bifunctional Boron-Lewis Acids - Thorough Investigation of the Adduct Formation with Pyrimidine”. European Journal of Inorganic Chemistry (2022): e202100842.

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