Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers

Müller F, Wickemeyer L, Schwabedissen J, Ertl M, Neumann B, Stammler H-G, Monkowius U, Mitzel NW (2022)
Dalton Transactions.

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Abstract / Bemerkung
Starting with 1,2-dibromobenzene and 1,2,3,4-tetrafluorobenzene, dimethyl(2-(trimethylstannyl)phenyl)phosphane, Me2P(o-C6H4)SnMe3, and dimethyl-[2,3,4,5-tetrafluoro-6-(trimethylstannyl)phenyl]phosphane, Me2P(o-C6F4)SnMe3, were synthesized and used in tin-gold exchange reactions to prepare two gold(I) dimers, bis[(2-dimethylphosphino)phenyl]di-gold(I), [Au2(mu-2-C6H4PMe2)2], and bis[(2-dimethylphosphino)-3,4,5,6-tetrafluorophenyl]di-gold(I), [Au2(mu-2-C6F4PMe2)2], respectively. Both tin precursor molecules, as well as the gold(I) complexes, were characterized by multinuclear NMR spectroscopy, CHN analysis and X-ray diffraction experiments. Both gold(I) dimers were further investigated by the means of computational as well as photophysical methods.
Erscheinungsjahr
2022
Zeitschriftentitel
Dalton Transactions
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/2960622

Zitieren

Müller F, Wickemeyer L, Schwabedissen J, et al. Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions. 2022.
Müller, F., Wickemeyer, L., Schwabedissen, J., Ertl, M., Neumann, B., Stammler, H. - G., Monkowius, U., et al. (2022). Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions. https://doi.org/10.1039/d1dt03658k
Müller, F., Wickemeyer, L., Schwabedissen, J., Ertl, M., Neumann, B., Stammler, H. - G., Monkowius, U., and Mitzel, N. W. (2022). Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions.
Müller, F., et al., 2022. Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions.
F. Müller, et al., “Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers”, Dalton Transactions, 2022.
Müller, F., Wickemeyer, L., Schwabedissen, J., Ertl, M., Neumann, B., Stammler, H.-G., Monkowius, U., Mitzel, N.W.: Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions. (2022).
Müller, Felix, Wickemeyer, Lucas, Schwabedissen, Jan, Ertl, Martin, Neumann, Beate, Stammler, Hans-Georg, Monkowius, Uwe, and Mitzel, Norbert W. “Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers”. Dalton Transactions (2022).

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