Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers
Müller F, Wickemeyer L, Schwabedissen J, Ertl M, Neumann B, Stammler H-G, Monkowius U, Mitzel NW (2022)
Dalton Transactions 51(5): 1955-1967.
Zeitschriftenaufsatz
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Autor*in
Müller, FelixUniBi;
Wickemeyer, LucasUniBi;
Schwabedissen, JanUniBi;
Ertl, Martin;
Neumann, BeateUniBi;
Stammler, Hans-GeorgUniBi;
Monkowius, Uwe;
Mitzel, Norbert W.UniBi
Abstract / Bemerkung
Starting with 1,2-dibromobenzene and 1,2,3,4-tetrafluorobenzene, dimethyl(2-(trimethylstannyl)phenyl)phosphane, Me2P(o-C6H4)SnMe3, and dimethyl-[2,3,4,5-tetrafluoro-6-(trimethylstannyl)phenyl]phosphane, Me2P(o-C6F4)SnMe3, were synthesized and used in tin-gold exchange reactions to prepare two gold(I) dimers, bis[(2-dimethylphosphino)phenyl]di-gold(I), [Au2(mu-2-C6H4PMe2)2], and bis[(2-dimethylphosphino)-3,4,5,6-tetrafluorophenyl]di-gold(I), [Au2(mu-2-C6F4PMe2)2], respectively. Both tin precursor molecules, as well as the gold(I) complexes, were characterized by multinuclear NMR spectroscopy, CHN analysis and X-ray diffraction experiments. Both gold(I) dimers were further investigated by the means of computational as well as photophysical methods.
Erscheinungsjahr
2022
Zeitschriftentitel
Dalton Transactions
Band
51
Ausgabe
5
Seite(n)
1955-1967
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/2960622
Zitieren
Müller F, Wickemeyer L, Schwabedissen J, et al. Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions. 2022;51(5):1955-1967.
Müller, F., Wickemeyer, L., Schwabedissen, J., Ertl, M., Neumann, B., Stammler, H. - G., Monkowius, U., et al. (2022). Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions, 51(5), 1955-1967. https://doi.org/10.1039/d1dt03658k
Müller, Felix, Wickemeyer, Lucas, Schwabedissen, Jan, Ertl, Martin, Neumann, Beate, Stammler, Hans-Georg, Monkowius, Uwe, and Mitzel, Norbert W. 2022. “Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers”. Dalton Transactions 51 (5): 1955-1967.
Müller, F., Wickemeyer, L., Schwabedissen, J., Ertl, M., Neumann, B., Stammler, H. - G., Monkowius, U., and Mitzel, N. W. (2022). Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions 51, 1955-1967.
Müller, F., et al., 2022. Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions, 51(5), p 1955-1967.
F. Müller, et al., “Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers”, Dalton Transactions, vol. 51, 2022, pp. 1955-1967.
Müller, F., Wickemeyer, L., Schwabedissen, J., Ertl, M., Neumann, B., Stammler, H.-G., Monkowius, U., Mitzel, N.W.: Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers. Dalton Transactions. 51, 1955-1967 (2022).
Müller, Felix, Wickemeyer, Lucas, Schwabedissen, Jan, Ertl, Martin, Neumann, Beate, Stammler, Hans-Georg, Monkowius, Uwe, and Mitzel, Norbert W. “Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(I) dimers”. Dalton Transactions 51.5 (2022): 1955-1967.
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Wickemeyer L (2022)
Bielefeld: Universität Bielefeld.
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Bielefeld: Universität Bielefeld.
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