An [FeIII30] molecular metal oxide

Dearle, Alice E; Cutler, Daniel J; Coletta, Marco; Lee, Edward; Dey, Sourav; Sanz, Sergio; Fraser, Hector W L; Nichol, Gary S; Rajaraman, Gopalan; Schnack, Jürgen; Cronin, Leroy; Brechin, Euan K

An [FeIII30] molecular metal oxide

Dearle AE, Cutler DJ, Coletta M, Lee E, Dey S, Sanz S, Fraser HWL, Nichol GS, Rajaraman G, Schnack J, Cronin L, et al. (2021)
Chemical Communications.

Zeitschriftenaufsatz | E-Veröff. vor dem Druck | Englisch

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DOI

https://doi.org/10.1039/d1cc06224g

Autor*in

Dearle, Alice E; Cutler, Daniel J; Coletta, Marco; Lee, Edward; Dey, Sourav; Sanz, Sergio; Fraser, Hector W L; Nichol, Gary S; Rajaraman, Gopalan; Schnack, Jürgen^UniBi ; Cronin, Leroy; Brechin, Euan K

Einrichtung

Fakultät für Physik > AG Theorie der Kondensierten Materie

Abstract / Bemerkung

Dissolution of FeBr3 in a mixture of acetonitrile and 3,4-lutidine in the presence of an amine results in the formation of an [Fe30] molecular metal oxide containing alternating layers of tetrahedral and octahedral FeIII ions. Mass spectrometry suggests the cluster is formed quickly and remains stable in solution, while magnetic measurements and DFT calculations reveal competing antiferromagnetic exchange interactions.

Erscheinungsjahr

2021

Zeitschriftentitel

Chemical Communications

eISSN

1364-548X

Page URI

https://pub.uni-bielefeld.de/record/2959622

Zitieren

Dearle AE, Cutler DJ, Coletta M, et al. An [FeIII30] molecular metal oxide. Chemical Communications. 2021.

Dearle, A. E., Cutler, D. J., Coletta, M., Lee, E., Dey, S., Sanz, S., Fraser, H. W. L., et al. (2021). An [FeIII30] molecular metal oxide. Chemical Communications. https://doi.org/10.1039/d1cc06224g

Dearle, Alice E, Cutler, Daniel J, Coletta, Marco, Lee, Edward, Dey, Sourav, Sanz, Sergio, Fraser, Hector W L, et al. 2021. “An [FeIII30] molecular metal oxide”. Chemical Communications.

Dearle, A. E., Cutler, D. J., Coletta, M., Lee, E., Dey, S., Sanz, S., Fraser, H. W. L., Nichol, G. S., Rajaraman, G., Schnack, J., et al. (2021). An [FeIII30] molecular metal oxide. Chemical Communications.

Dearle, A.E., et al., 2021. An [FeIII30] molecular metal oxide. Chemical Communications.

A.E. Dearle, et al., “An [FeIII30] molecular metal oxide”, Chemical Communications, 2021.

Dearle, A.E., Cutler, D.J., Coletta, M., Lee, E., Dey, S., Sanz, S., Fraser, H.W.L., Nichol, G.S., Rajaraman, G., Schnack, J., Cronin, L., Brechin, E.K.: An [FeIII30] molecular metal oxide. Chemical Communications. (2021).

Dearle, Alice E, Cutler, Daniel J, Coletta, Marco, Lee, Edward, Dey, Sourav, Sanz, Sergio, Fraser, Hector W L, Nichol, Gary S, Rajaraman, Gopalan, Schnack, Jürgen, Cronin, Leroy, and Brechin, Euan K. “An [FeIII30] molecular metal oxide”. Chemical Communications (2021).

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