Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives

Ghadwal R, Rottschäfer D, Glodde T, Neumann B, Stammler H-G, Andrada D (Accepted)
Angewandte Chemie International Edition .

Zeitschriftenaufsatz | Angenommen | Englisch
 
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Abstract / Bemerkung
1,4-Diarsinine-1,4-diide compound [(ADC Ph )As] 2 ( 5 ) (ADC Ph = {C(DippN)} 2 CPh, Dipp = 2,6- i Pr 2 C 6 H 3 ) with a planar C 4 As 2 -ring fused between two 1,3-imidazole scaffolds has been isolated as a red crystalline solid. Compound 5 , formally comprising an 8pi-electron C 4 As 2 -ring, is antiaromatic and undergoes 2e-oxidation with AgOTf to form the 6pi-electron aromatic system [(ADC Ph )As] 2 (OTf) 2 ( 6 ). © 2021 Wiley-VCH GmbH.
Erscheinungsjahr
2021
Zeitschriftentitel
Angewandte Chemie International Edition
eISSN
1521-3773
Page URI
https://pub.uni-bielefeld.de/record/2955247

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Ghadwal R, Rottschäfer D, Glodde T, Neumann B, Stammler H-G, Andrada D. Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition . Accepted.
Ghadwal, R., Rottschäfer, D., Glodde, T., Neumann, B., Stammler, H. - G., & Andrada, D. (Accepted). Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition . https://doi.org/10.1002/anie.202105835
Ghadwal, R., Rottschäfer, D., Glodde, T., Neumann, B., Stammler, H. - G., and Andrada, D. (Accepted). Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition .
Ghadwal, R., et al., Accepted. Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition .
R. Ghadwal, et al., “Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives”, Angewandte Chemie International Edition , Accepted.
Ghadwal, R., Rottschäfer, D., Glodde, T., Neumann, B., Stammler, H.-G., Andrada, D.: Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition . (Accepted).
Ghadwal, Rajendra, Rottschäfer, Dennis, Glodde, Timo, Neumann, Beate, Stammler, Hans-Georg, and Andrada, Diego. “Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives”. Angewandte Chemie International Edition (Accepted).

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