Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes

Weitkamp R, Neumann B, Stammler H-G, Hoge B (Accepted)
Chemistry - A European Journal 27(42): 10807-10825.

Zeitschriftenaufsatz | Angenommen | Englisch
 
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Abstract / Bemerkung
The renaissance of Bronsted superbases is primarily based on their pronounced capability for a large variety of chemical transformations under mild reaction conditions. Four major set screws are available for the selective tuning of the basicity: the nature of the basic center (N, P, ), the degree of electron donation by substituents to the central atom, the possibility of charge delocalization, and the energy gain by hydrogen bonding. Within the past decades, a plethora of neutral electron-rich phosphine and phosphazene bases appeared in the literature. Their outstanding properties and advantages over inorganic or charged bases have made them now indispensable as auxiliary bases in deprotonation processes. Also, their utilization in catalysis or as ligands in coordination chemistry is highlighted due to broad-spread interest. Here we give an update of the chemistry of basic phosphines and phosphazenes. © 2021 Wiley-VCH GmbH.
Erscheinungsjahr
2021
Zeitschriftentitel
Chemistry - A European Journal
Band
27
Ausgabe
42
Seite(n)
10807-10825
eISSN
1521-3765
Finanzierungs-Informationen
Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.
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https://pub.uni-bielefeld.de/record/2955237

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Weitkamp R, Neumann B, Stammler H-G, Hoge B. Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes. Chemistry - A European Journal. Accepted;27(42):10807-10825.
Weitkamp, R., Neumann, B., Stammler, H. - G., & Hoge, B. (Accepted). Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes. Chemistry - A European Journal, 27(42), 10807-10825. https://doi.org/10.1002/chem.202101065
Weitkamp, R., Neumann, B., Stammler, H. - G., and Hoge, B. (Accepted). Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes. Chemistry - A European Journal 27, 10807-10825.
Weitkamp, R., et al., Accepted. Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes. Chemistry - A European Journal, 27(42), p 10807-10825.
R. Weitkamp, et al., “Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes”, Chemistry - A European Journal, vol. 27, Accepted, pp. 10807-10825.
Weitkamp, R., Neumann, B., Stammler, H.-G., Hoge, B.: Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes. Chemistry - A European Journal. 27, 10807-10825 (Accepted).
Weitkamp, Robin, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes”. Chemistry - A European Journal 27.42 (Accepted): 10807-10825.
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2022-07-04T13:30:32Z
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