The Synthesis and Characterisation of a Molecular Sea-Serpent: Studies of a {Cr24Cu7} Chain
Winpenny R, Alotaibi R, Fowler J, Lockyer S, Timco G, Collison D, Schnack J (2021)
Angewandte Chemie International Edition.
A finite chain of thirty-one paramagnetic centers is reported, synthesised by reaction of hydrated chromium fluoride, copper carbonate and pivalic acid in the presence of 1,4,7,10-tetrazacyclododecane (cyclen). Magnetic studies show predominantly anti-ferromagnetic exchange leading to a high density of low-lying spin sites and large saturation fields.
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