N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR
Ghadwal R, Roesky HW, Schulzke C, Granitzka M (2010)
Organometallics 29(23): 6329-6333.
Zeitschriftenaufsatz
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Autor*in
Ghadwal, RajendraUniBi 
;
Roesky, Herbert W.;
Schulzke, Carola;
Granitzka, Markus
;
Roesky, Herbert W.;
Schulzke, Carola;
Granitzka, MarkusAbstract / Bemerkung
N-Heterocyclic carbene stabilized dichlorosilaimine IPr·Cl2Si═N(Diip) (2) has been synthesized by the reaction of dichlorosilylene IPr·SiCl2 (1) with bis(2,6-diisopropylphenyl)carbodiimide (IPr = :C[N(2,6-i-Pr2-C6H3)CH]2, Diip = 2,6-i-Pr2-C6H3). Reaction of 1 with terphenyl azides also affords dichlorosilaimines IPr·Cl2Si═N(2,6-Diip2-C6H3) (3) and IPr·Cl2Si═N(2,6-Triip2-C6H3) (4) (Triip = 2,4,6-i-Pr3-C6H2). Compounds 2−4 are stable under an inert atmosphere and were characterized by elemental analysis and NMR spectroscopic studies. The molecular structures of 2−4 were determined by single-crystal X-ray analysis.
Erscheinungsjahr
2010
Zeitschriftentitel
Organometallics
Band
29
Ausgabe
23
Seite(n)
6329-6333
ISSN
0276-7333
eISSN
1520-6041
Page URI
https://pub.uni-bielefeld.de/record/2951060
Zitieren
Ghadwal R, Roesky HW, Schulzke C, Granitzka M. N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR. Organometallics. 2010;29(23):6329-6333.
Ghadwal, R., Roesky, H. W., Schulzke, C., & Granitzka, M. (2010). N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR. Organometallics, 29(23), 6329-6333. https://doi.org/10.1021/om100737v
Ghadwal, Rajendra, Roesky, Herbert W., Schulzke, Carola, and Granitzka, Markus. 2010. “N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR”. Organometallics 29 (23): 6329-6333.
Ghadwal, R., Roesky, H. W., Schulzke, C., and Granitzka, M. (2010). N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR. Organometallics 29, 6329-6333.
Ghadwal, R., et al., 2010. N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR. Organometallics, 29(23), p 6329-6333.
R. Ghadwal, et al., “N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR”, Organometallics, vol. 29, 2010, pp. 6329-6333.
Ghadwal, R., Roesky, H.W., Schulzke, C., Granitzka, M.: N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR. Organometallics. 29, 6329-6333 (2010).
Ghadwal, Rajendra, Roesky, Herbert W., Schulzke, Carola, and Granitzka, Markus. “N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR”. Organometallics 29.23 (2010): 6329-6333.
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