A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene

Ghadwal R, Roesky HW, Granitzka M, Stalke D (2010)
Journal of the American Chemical Society 132(29): 10018-10020.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Ghadwal, RajendraUniBi ; Roesky, Herbert W.; Granitzka, Markus; Stalke, Dietmar
Abstract / Bemerkung
Reaction of IPr·SiCl2 (1) [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene] with 1-azidoadamantane leads to functionalized N-heterocyclic carbene (NHC) 2. Silyl-substituted NHC 2 reacts easily with 1-azidoadamantane to form triazene 3, in which the exocyclic C═N bond is slightly shorter than those of regular NHC-derived triazines. 2 could serve as a promising ligand for transition metals.
Erscheinungsjahr
2010
Zeitschriftentitel
Journal of the American Chemical Society
Band
132
Ausgabe
29
Seite(n)
10018-10020
ISSN
0002-7863
eISSN
1520-5126
Page URI
https://pub.uni-bielefeld.de/record/2951056

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Ghadwal R, Roesky HW, Granitzka M, Stalke D. A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene. Journal of the American Chemical Society. 2010;132(29):10018-10020.
Ghadwal, R., Roesky, H. W., Granitzka, M., & Stalke, D. (2010). A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene. Journal of the American Chemical Society, 132(29), 10018-10020. https://doi.org/10.1021/ja104386g
Ghadwal, R., Roesky, H. W., Granitzka, M., and Stalke, D. (2010). A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene. Journal of the American Chemical Society 132, 10018-10020.
Ghadwal, R., et al., 2010. A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene. Journal of the American Chemical Society, 132(29), p 10018-10020.
R. Ghadwal, et al., “A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene”, Journal of the American Chemical Society, vol. 132, 2010, pp. 10018-10020.
Ghadwal, R., Roesky, H.W., Granitzka, M., Stalke, D.: A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene. Journal of the American Chemical Society. 132, 10018-10020 (2010).
Ghadwal, Rajendra, Roesky, Herbert W., Granitzka, Markus, and Stalke, Dietmar. “A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene”. Journal of the American Chemical Society 132.29 (2010): 10018-10020.

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