Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride
Ghadwal R, Azhakar R, Roesky HW, Pröpper K, Dittrich B, Klein S, Frenking G (2011)
Journal of the American Chemical Society 133(44): 17552-17555.
Zeitschriftenaufsatz
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Autor*in
Ghadwal, RajendraUniBi 
;
Azhakar, Ramachandran;
Roesky, Herbert W.;
Pröpper, Kevin;
Dittrich, Birger;
Klein, Susanne;
Frenking, Gernot
;
Azhakar, Ramachandran;
Roesky, Herbert W.;
Pröpper, Kevin;
Dittrich, Birger;
Klein, Susanne;
Frenking, GernotAbstract / Bemerkung
A stable silicon analogue of an acid anhydride {PhC(ButN)2}Si{═O·B(C6F5)3}O–Si(H){═O·B(C6F5)3}{(NBut)(HNBut)CPh} (4) with a O═Si–O–Si═O core has been prepared by treating monochlorosilylene PhC(ButN)2SiCl (1) with H2O·B(C6F5)3 in the presence of NHC (NHC = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene). Compound 4 has been characterized by elemental analysis and multinuclear NMR spectroscopic investigations. The molecular structure of 4 has been established by single-crystal X-ray diffraction studies, and DFT calculations support the experimental results.
Erscheinungsjahr
2011
Zeitschriftentitel
Journal of the American Chemical Society
Band
133
Ausgabe
44
Seite(n)
17552-17555
ISSN
0002-7863
eISSN
1520-5126
Page URI
https://pub.uni-bielefeld.de/record/2951050
Zitieren
Ghadwal R, Azhakar R, Roesky HW, et al. Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride. Journal of the American Chemical Society. 2011;133(44):17552-17555.
Ghadwal, R., Azhakar, R., Roesky, H. W., Pröpper, K., Dittrich, B., Klein, S., & Frenking, G. (2011). Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride. Journal of the American Chemical Society, 133(44), 17552-17555. https://doi.org/10.1021/ja206702e
Ghadwal, Rajendra, Azhakar, Ramachandran, Roesky, Herbert W., Pröpper, Kevin, Dittrich, Birger, Klein, Susanne, and Frenking, Gernot. 2011. “Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride”. Journal of the American Chemical Society 133 (44): 17552-17555.
Ghadwal, R., Azhakar, R., Roesky, H. W., Pröpper, K., Dittrich, B., Klein, S., and Frenking, G. (2011). Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride. Journal of the American Chemical Society 133, 17552-17555.
Ghadwal, R., et al., 2011. Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride. Journal of the American Chemical Society, 133(44), p 17552-17555.
R. Ghadwal, et al., “Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride”, Journal of the American Chemical Society, vol. 133, 2011, pp. 17552-17555.
Ghadwal, R., Azhakar, R., Roesky, H.W., Pröpper, K., Dittrich, B., Klein, S., Frenking, G.: Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride. Journal of the American Chemical Society. 133, 17552-17555 (2011).
Ghadwal, Rajendra, Azhakar, Ramachandran, Roesky, Herbert W., Pröpper, Kevin, Dittrich, Birger, Klein, Susanne, and Frenking, Gernot. “Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride”. Journal of the American Chemical Society 133.44 (2011): 17552-17555.
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