A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms

Ghadwal R, Roesky HW, Pröpper K, Dittrich B, Klein S, Frenking G (2011)
Angewandte Chemie International Edition 50(23): 5374-5378.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Ghadwal, RajendraUniBi ; Roesky, Herbert W.; Pröpper, Kevin; Dittrich, Birger; Klein, Susanne; Frenking, Gernot
Abstract / Bemerkung
A specialty of silicon: A stable dimeric silaisonitrile (ArNSi:)2 (see picture; Ar=2,6-bis(2,4,6-triisopropylphenyl)phenyl) was prepared by the reduction of dichlorosilaimine IPr⋅Cl2Si NAr with KC8. The dimer is the first base-free disilylene with two-coordinate silicon atoms; reaction with trimethylsilyl azide affords the first bis(silaimine) (ArNSi NSiMe3)2 with three-coordinate silicon atoms.
Stichworte
silylenes; X-ray diffraction; density functional calculations; main-group elements; multiple bonds
Erscheinungsjahr
2011
Zeitschriftentitel
Angewandte Chemie International Edition
Band
50
Ausgabe
23
Seite(n)
5374-5378
ISSN
1433-7851
Page URI
https://pub.uni-bielefeld.de/record/2951049

Zitieren

Ghadwal R, Roesky HW, Pröpper K, Dittrich B, Klein S, Frenking G. A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms. Angewandte Chemie International Edition. 2011;50(23):5374-5378.
Ghadwal, R., Roesky, H. W., Pröpper, K., Dittrich, B., Klein, S., & Frenking, G. (2011). A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms. Angewandte Chemie International Edition, 50(23), 5374-5378. https://doi.org/10.1002/anie.201101320
Ghadwal, R., Roesky, H. W., Pröpper, K., Dittrich, B., Klein, S., and Frenking, G. (2011). A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms. Angewandte Chemie International Edition 50, 5374-5378.
Ghadwal, R., et al., 2011. A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms. Angewandte Chemie International Edition, 50(23), p 5374-5378.
R. Ghadwal, et al., “A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms”, Angewandte Chemie International Edition, vol. 50, 2011, pp. 5374-5378.
Ghadwal, R., Roesky, H.W., Pröpper, K., Dittrich, B., Klein, S., Frenking, G.: A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms. Angewandte Chemie International Edition. 50, 5374-5378 (2011).
Ghadwal, Rajendra, Roesky, Herbert W., Pröpper, Kevin, Dittrich, Birger, Klein, Susanne, and Frenking, Gernot. “A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms”. Angewandte Chemie International Edition 50.23 (2011): 5374-5378.

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