Lewis base mediated dismutation of trichlorosilane

Singh, Amit Pratap; Ghadwal, Rajendra; Roesky, Herbert W.; Holstein, Julian J.; Dittrich, Birger; Demers, Jean-Philippe; Chevelkov, Veniamin; Lange, Adam

Lewis base mediated dismutation of trichlorosilane

Singh AP, Ghadwal R, Roesky HW, Holstein JJ, Dittrich B, Demers J-P, Chevelkov V, Lange A (2012)
Chemical Communications 48(61): 7574.

Zeitschriftenaufsatz | Veröffentlicht | Englisch

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DOI

https://doi.org/10.1039/c2cc33835a

Autor*in

Singh, Amit Pratap; Ghadwal, Rajendra^UniBi ; Roesky, Herbert W.; Holstein, Julian J.; Dittrich, Birger; Demers, Jean-Philippe; Chevelkov, Veniamin; Lange, Adam

Einrichtung

Fakultät für Chemie > Anorganische Chemie und Strukturchemie

Abstract / Bemerkung

An abnormal N-heterocyclic carbene (aNHC) has been used as a Lewis base to initiate dismutation of trichlorosilane. This report presents the reactivity differences of a normal N-heterocyclic carbene (NHC) versus aNHC with heavier group 14 elements. Three novel compounds (NHC)2·SiCl2H2 (2), aNHC·SiCl2H2 (3), and aNHC·GeCl2 (4) have been synthesized and characterized by single crystal X-ray analysis, solid-state NMR and DFT calculations.

Erscheinungsjahr

2012

Zeitschriftentitel

Chemical Communications

Band

Ausgabe

Art.-Nr.

7574

ISSN

1359-7345

eISSN

1364-548X

Page URI

https://pub.uni-bielefeld.de/record/2951045

Zitieren

Singh AP, Ghadwal R, Roesky HW, et al. Lewis base mediated dismutation of trichlorosilane. Chemical Communications. 2012;48(61): 7574.

Singh, A. P., Ghadwal, R., Roesky, H. W., Holstein, J. J., Dittrich, B., Demers, J. - P., Chevelkov, V., et al. (2012). Lewis base mediated dismutation of trichlorosilane. Chemical Communications, 48(61), 7574. https://doi.org/10.1039/c2cc33835a

Singh, Amit Pratap, Ghadwal, Rajendra, Roesky, Herbert W., Holstein, Julian J., Dittrich, Birger, Demers, Jean-Philippe, Chevelkov, Veniamin, and Lange, Adam. 2012. “Lewis base mediated dismutation of trichlorosilane”. Chemical Communications 48 (61): 7574.

Singh, A. P., Ghadwal, R., Roesky, H. W., Holstein, J. J., Dittrich, B., Demers, J. - P., Chevelkov, V., and Lange, A. (2012). Lewis base mediated dismutation of trichlorosilane. Chemical Communications 48:7574.

Singh, A.P., et al., 2012. Lewis base mediated dismutation of trichlorosilane. Chemical Communications, 48(61): 7574.

A.P. Singh, et al., “Lewis base mediated dismutation of trichlorosilane”, Chemical Communications, vol. 48, 2012, : 7574.

Singh, A.P., Ghadwal, R., Roesky, H.W., Holstein, J.J., Dittrich, B., Demers, J.-P., Chevelkov, V., Lange, A.: Lewis base mediated dismutation of trichlorosilane. Chemical Communications. 48, : 7574 (2012).

Singh, Amit Pratap, Ghadwal, Rajendra, Roesky, Herbert W., Holstein, Julian J., Dittrich, Birger, Demers, Jean-Philippe, Chevelkov, Veniamin, and Lange, Adam. “Lewis base mediated dismutation of trichlorosilane”. Chemical Communications 48.61 (2012): 7574.

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