Donor–acceptor stabilized silaformyl chloride
Ghadwal R, Azhakar R, Roesky HW, Pröpper K, Dittrich B, Goedecke C, Frenking G (2012)
Chemical Communications 48(66): 8186.
Zeitschriftenaufsatz
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Autor*in
Ghadwal, RajendraUniBi 
;
Azhakar, Ramachandran;
Roesky, Herbert W.;
Pröpper, Kevin;
Dittrich, Birger;
Goedecke, Catharina;
Frenking, Gernot
;
Azhakar, Ramachandran;
Roesky, Herbert W.;
Pröpper, Kevin;
Dittrich, Birger;
Goedecke, Catharina;
Frenking, GernotAbstract / Bemerkung
Formyl chloride (H(Cl)C[double bond, length as m-dash]O) is unstable at room temperature and decomposes to HCl and CO. Silicon analogue of formyl chloride, silaformyl chloride IPr·SiH(Cl)[double bond, length as m-dash]O·B(C6F5)3 (3) (IPr = 1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene), was stabilized by Lewis donor–acceptor ligands. Compound 3 is not only the first stable acyclic silacarbonyl compound but also the first silacarbonyl halide reported so far.
Erscheinungsjahr
2012
Zeitschriftentitel
Chemical Communications
Band
48
Ausgabe
66
Art.-Nr.
8186
ISSN
1359-7345
eISSN
1364-548X
Page URI
https://pub.uni-bielefeld.de/record/2951041
Zitieren
Ghadwal R, Azhakar R, Roesky HW, et al. Donor–acceptor stabilized silaformyl chloride. Chemical Communications. 2012;48(66): 8186.
Ghadwal, R., Azhakar, R., Roesky, H. W., Pröpper, K., Dittrich, B., Goedecke, C., & Frenking, G. (2012). Donor–acceptor stabilized silaformyl chloride. Chemical Communications, 48(66), 8186. https://doi.org/10.1039/c2cc32887a
Ghadwal, Rajendra, Azhakar, Ramachandran, Roesky, Herbert W., Pröpper, Kevin, Dittrich, Birger, Goedecke, Catharina, and Frenking, Gernot. 2012. “Donor–acceptor stabilized silaformyl chloride”. Chemical Communications 48 (66): 8186.
Ghadwal, R., Azhakar, R., Roesky, H. W., Pröpper, K., Dittrich, B., Goedecke, C., and Frenking, G. (2012). Donor–acceptor stabilized silaformyl chloride. Chemical Communications 48:8186.
Ghadwal, R., et al., 2012. Donor–acceptor stabilized silaformyl chloride. Chemical Communications, 48(66): 8186.
R. Ghadwal, et al., “Donor–acceptor stabilized silaformyl chloride”, Chemical Communications, vol. 48, 2012, : 8186.
Ghadwal, R., Azhakar, R., Roesky, H.W., Pröpper, K., Dittrich, B., Goedecke, C., Frenking, G.: Donor–acceptor stabilized silaformyl chloride. Chemical Communications. 48, : 8186 (2012).
Ghadwal, Rajendra, Azhakar, Ramachandran, Roesky, Herbert W., Pröpper, Kevin, Dittrich, Birger, Goedecke, Catharina, and Frenking, Gernot. “Donor–acceptor stabilized silaformyl chloride”. Chemical Communications 48.66 (2012): 8186.
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