An access to base-stabilized three-membered silicon heterocycles
Azhakar R, Roesky HW, Ghadwal R, Holstein JJ, Dittrich B (2012)
Dalton Transactions 41(32): 9601.
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Autor*in
Azhakar, Ramachandran;
Roesky, Herbert W.;
Ghadwal, RajendraUniBi 
;
Holstein, Julian J.;
Dittrich, Birger
;
Holstein, Julian J.;
Dittrich, BirgerAbstract / Bemerkung
The three-membered silacyclic ring compounds LSi[N2(Ph)2]tBu (1), LSi[HCN(Ph)2]tBu (2) and LSi[C2(Ph)2]tBu (3) were obtained by the treatment of base stabilized monoalkylsilylenes LSitBu (L = PhC(NtBu)2) with PhN[double bond, length as m-dash]NPh, PhN[double bond, length as m-dash]CHPh and PhC[triple bond, length as m-dash]CPh. The reaction of PhN[double bond, length as m-dash]NPh and PhC[triple bond, length as m-dash]CPh with LSitBu shows a different reactivity pattern with base stabilized monochlorosilylene LSiCl. The arrangement of the three-membered ring (SiNN) in 1 is the first structurally isolated example of a siladiaziridine compound.
Erscheinungsjahr
2012
Zeitschriftentitel
Dalton Transactions
Band
41
Ausgabe
32
Art.-Nr.
9601
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/2951040
Zitieren
Azhakar R, Roesky HW, Ghadwal R, Holstein JJ, Dittrich B. An access to base-stabilized three-membered silicon heterocycles. Dalton Transactions. 2012;41(32): 9601.
Azhakar, R., Roesky, H. W., Ghadwal, R., Holstein, J. J., & Dittrich, B. (2012). An access to base-stabilized three-membered silicon heterocycles. Dalton Transactions, 41(32), 9601. https://doi.org/10.1039/c2dt31326j
Azhakar, Ramachandran, Roesky, Herbert W., Ghadwal, Rajendra, Holstein, Julian J., and Dittrich, Birger. 2012. “An access to base-stabilized three-membered silicon heterocycles”. Dalton Transactions 41 (32): 9601.
Azhakar, R., Roesky, H. W., Ghadwal, R., Holstein, J. J., and Dittrich, B. (2012). An access to base-stabilized three-membered silicon heterocycles. Dalton Transactions 41:9601.
Azhakar, R., et al., 2012. An access to base-stabilized three-membered silicon heterocycles. Dalton Transactions, 41(32): 9601.
R. Azhakar, et al., “An access to base-stabilized three-membered silicon heterocycles”, Dalton Transactions, vol. 41, 2012, : 9601.
Azhakar, R., Roesky, H.W., Ghadwal, R., Holstein, J.J., Dittrich, B.: An access to base-stabilized three-membered silicon heterocycles. Dalton Transactions. 41, : 9601 (2012).
Azhakar, Ramachandran, Roesky, Herbert W., Ghadwal, Rajendra, Holstein, Julian J., and Dittrich, Birger. “An access to base-stabilized three-membered silicon heterocycles”. Dalton Transactions 41.32 (2012): 9601.
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