Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting

Sharma MK, Ebeler F, Glodde T, Neumann B, Stammler H-G, Ghadwal R (2021)
Journal of the American Chemical Society 143(1): 121–125.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
The cyclic Ge(I) compound [(ADCPh)Ge]2 (4) (ADCPh = {CN(Dipp)}2CPh, Dipp = 2,6-iPr2C6H3) containing a 6π-electron C4Ge2 framework has been isolated as a red crystalline solid. CASSCF calculations reveal a closed-shell singlet ground state for 4 with a considerable diradical character (y = 34%). Thus, the diradicaloid 4 readily splits dihydrogen at room temperature to yield the elusive bis-hydridogermylene [(ADCPh)GeH]2 (5).
Erscheinungsjahr
2021
Zeitschriftentitel
Journal of the American Chemical Society
Band
143
Ausgabe
1
Seite(n)
121–125
ISSN
0002-7863
eISSN
1520-5126
Page URI
https://pub.uni-bielefeld.de/record/2949914

Zitieren

Sharma MK, Ebeler F, Glodde T, Neumann B, Stammler H-G, Ghadwal R. Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting. Journal of the American Chemical Society. 2021;143(1):121–125.
Sharma, M. K., Ebeler, F., Glodde, T., Neumann, B., Stammler, H. - G., & Ghadwal, R. (2021). Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting. Journal of the American Chemical Society, 143(1), 121–125. doi:10.1021/jacs.0c11828
Sharma, M. K., Ebeler, F., Glodde, T., Neumann, B., Stammler, H. - G., and Ghadwal, R. (2021). Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting. Journal of the American Chemical Society 143, 121–125.
Sharma, M.K., et al., 2021. Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting. Journal of the American Chemical Society, 143(1), p 121–125.
M.K. Sharma, et al., “Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting”, Journal of the American Chemical Society, vol. 143, 2021, pp. 121–125.
Sharma, M.K., Ebeler, F., Glodde, T., Neumann, B., Stammler, H.-G., Ghadwal, R.: Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting. Journal of the American Chemical Society. 143, 121–125 (2021).
Sharma, Mahendra Kumar, Ebeler, Falk, Glodde, Timo, Neumann, Beate, Stammler, Hans-Georg, and Ghadwal, Rajendra. “Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting”. Journal of the American Chemical Society 143.1 (2021): 121–125.

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