Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions
Binks BP, Bago Rodriguez AM, Schober L, Hinzmann A, Gröger H (2021)
Angewandte Chemie International Edition 60(3): 1450-1457.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
anie.202013171(1).groeger.pdf
1.46 MB
Autor*in
Binks, Bernard Paul;
Bago Rodriguez, Ana Maria;
Schober, LukasUniBi;
Hinzmann, AlessaUniBi ;
Gröger, HaraldUniBi
Einrichtung
Abstract / Bemerkung
Pickering emulsion systems have emerged as platforms for the synthesis of organic molecules in biphasic biocatalysis. Herein, the catalytic performance was evaluated for biotransformation using whole cells exemplified for the dehydration of n -octanaloxime to n -octanenitrile catalysed by an aldoxime dehydratase (OxdB) overexpressed in E. coli. This study was carried out in Pickering emulsions stabilised solely with silica particles of different hydrophobicity. We correlate, for the first time, the properties of the emulsions with the conversion of the reaction, thus gaining an insight into the impact of the particle wettability and particle concentration. When comparing two emulsions of different type with similar stability and droplet diameter, the oil-in-water (o/w) system displayed a higher conversion than the water-in-oil (w/o) system, despite the conversion in both cases being higher than that in a "classic" two-phase system. Furthermore, an increase in particle concentration prior to emulsification resulted in an increase of the interfacial area and hence a higher conversion.
Erscheinungsjahr
2021
Zeitschriftentitel
Angewandte Chemie International Edition
Band
60
Ausgabe
3
Seite(n)
1450-1457
Urheberrecht / Lizenzen
eISSN
1521-3773
Finanzierungs-Informationen
Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.
Page URI
https://pub.uni-bielefeld.de/record/2948758
Zitieren
Binks BP, Bago Rodriguez AM, Schober L, Hinzmann A, Gröger H. Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions. Angewandte Chemie International Edition. 2021;60(3):1450-1457.
Binks, B. P., Bago Rodriguez, A. M., Schober, L., Hinzmann, A., & Gröger, H. (2021). Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions. Angewandte Chemie International Edition, 60(3), 1450-1457. https://doi.org/10.1002/anie.202013171
Binks, Bernard Paul, Bago Rodriguez, Ana Maria, Schober, Lukas, Hinzmann, Alessa, and Gröger, Harald. 2021. “Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions”. Angewandte Chemie International Edition 60 (3): 1450-1457.
Binks, B. P., Bago Rodriguez, A. M., Schober, L., Hinzmann, A., and Gröger, H. (2021). Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions. Angewandte Chemie International Edition 60, 1450-1457.
Binks, B.P., et al., 2021. Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions. Angewandte Chemie International Edition, 60(3), p 1450-1457.
B.P. Binks, et al., “Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions”, Angewandte Chemie International Edition, vol. 60, 2021, pp. 1450-1457.
Binks, B.P., Bago Rodriguez, A.M., Schober, L., Hinzmann, A., Gröger, H.: Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions. Angewandte Chemie International Edition. 60, 1450-1457 (2021).
Binks, Bernard Paul, Bago Rodriguez, Ana Maria, Schober, Lukas, Hinzmann, Alessa, and Gröger, Harald. “Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions”. Angewandte Chemie International Edition 60.3 (2021): 1450-1457.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Creative Commons Namensnennung 4.0 International Public License (CC-BY 4.0):
Volltext(e)
Name
anie.202013171(1).groeger.pdf
1.46 MB
Access Level
Open Access
Zuletzt Hochgeladen
2021-02-05T10:56:45Z
MD5 Prüfsumme
6d6b69cb4e82588c54978bd9c82a025d
Daten bereitgestellt von European Bioinformatics Institute (EBI)
Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
References
Daten bereitgestellt von Europe PubMed Central.
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Quellen
PMID: 33119950
PubMed | Europe PMC
Suchen in