The nature of chalcogen-bonding-type tellurium-nitrogen interactions: a first experimental structure from the gas phase

Glodde T, Vishnevskiy Y, Zimmermann L, Neumann B, Stammler H-G, Mitzel NW (2021)
Angewandte Chemie International Edition 60(3): 1519-1523.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
(C 6 F 5 )Te(CH 2 ) 3 NMe 2 ( 1 ), a perfluoro-phe-nyltellurium deriva-tive capable of forming intra-molecular N∙∙∙Te interactions, was prepared and charac-terized. The donor-free reference substance (C 6 F 5 )TeMe( 2 ) and the unsupported adduct (C 6 F 5 )(Me)Te∙NMe 2 Et ( 2b ) were studied in parallel. Mole-cular structures of 1 , 2 and 2b were determined by single crystal X-ray diffraction and for 1 and 2 by gas-phase electron diffraction. The structure of 1 shows N∙∙∙Te distan-ces of 2.639(1) A (solid) and 2.694(53) A (gas). Ab initio plus NBO and QTAIM calculations show significant charge transfer effects within the N∙∙∙Te interactions and indicate sigma-hole interactions. © 2020 Wiley-VCH GmbH.
Erscheinungsjahr
2021
Zeitschriftentitel
Angewandte Chemie International Edition
Band
60
Ausgabe
3
Seite(n)
1519-1523
eISSN
1521-3773
Page URI
https://pub.uni-bielefeld.de/record/2948410

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Glodde T, Vishnevskiy Y, Zimmermann L, Neumann B, Stammler H-G, Mitzel NW. The nature of chalcogen-bonding-type tellurium-nitrogen interactions: a first experimental structure from the gas phase. Angewandte Chemie International Edition. 2021;60(3):1519-1523.
Glodde, T., Vishnevskiy, Y., Zimmermann, L., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2021). The nature of chalcogen-bonding-type tellurium-nitrogen interactions: a first experimental structure from the gas phase. Angewandte Chemie International Edition, 60(3), 1519-1523. doi:10.1002/anie.202013480
Glodde, T., Vishnevskiy, Y., Zimmermann, L., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2021). The nature of chalcogen-bonding-type tellurium-nitrogen interactions: a first experimental structure from the gas phase. Angewandte Chemie International Edition 60, 1519-1523.
Glodde, T., et al., 2021. The nature of chalcogen-bonding-type tellurium-nitrogen interactions: a first experimental structure from the gas phase. Angewandte Chemie International Edition, 60(3), p 1519-1523.
T. Glodde, et al., “The nature of chalcogen-bonding-type tellurium-nitrogen interactions: a first experimental structure from the gas phase”, Angewandte Chemie International Edition, vol. 60, 2021, pp. 1519-1523.
Glodde, T., Vishnevskiy, Y., Zimmermann, L., Neumann, B., Stammler, H.-G., Mitzel, N.W.: The nature of chalcogen-bonding-type tellurium-nitrogen interactions: a first experimental structure from the gas phase. Angewandte Chemie International Edition. 60, 1519-1523 (2021).
Glodde, Timo, Vishnevskiy, Yury, Zimmermann, Lars, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “The nature of chalcogen-bonding-type tellurium-nitrogen interactions: a first experimental structure from the gas phase”. Angewandte Chemie International Edition 60.3 (2021): 1519-1523.
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