Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants

Schwabedissen, Jan; Glodde, Timo; Vishnevskiy, Yury; Stammler, Hans-Georg; Flierl, Lukas; Kornath, Andreas J.; Mitzel, Norbert W.

Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants

Schwabedissen J, Glodde T, Vishnevskiy Y, Stammler H-G, Flierl L, Kornath AJ, Mitzel NW (2020)
ChemistryOpen 9(9): 921-928.

Zeitschriftenaufsatz | Veröffentlicht | Englisch

Download

open.mitzel.202000172.pdf 1.04 MB

DOI

https://doi.org/10.1002/open.202000172

URN

urn:nbn:de:0070-pub-29458700

Autor*in

Schwabedissen, Jan^UniBi; Glodde, Timo^UniBi; Vishnevskiy, Yury^UniBi; Stammler, Hans-Georg^UniBi; Flierl, Lukas; Kornath, Andreas J.; Mitzel, Norbert W.^UniBi

Einrichtung

Fakultät für Chemie > Anorganische Chemie und Strukturchemie

Abstract / Bemerkung

The refrigerant trans‐1,3,3,3‐tetrafluoropropene (HFO‐1234ze) is used as a replacement for former cooling agents that have been phased‐out due to their global warming potential or ozone depleting potential. Although it is used on a large scale, only a few vibrational data and no structural data of HFO‐1234ze are known. We report structure determinations based on low‐temperature single‐crystal X‐ray diffraction data as well as gas‐phase diffraction data of HFO‐1234ze and HFO‐1234yf (2,3,3,3‐tetrafluoropropene). Furthermore, vibrational spectra of HFO‐1234ze in all phases are described. The results are discussed together with quantum‐chemical calculations on the PBE0/cc‐pVTZ level of theory. Combustion experiments of HFO‐1234ze show carbonyl difluoride, carbon dioxide and hydrogen fluoride to be the main combustion products.

Erscheinungsjahr

2020

Zeitschriftentitel

ChemistryOpen

Band

Ausgabe

Seite(n)

921-928

Urheberrecht / Lizenzen

Creative Commons Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International (CC BY-NC-ND 4.0)

eISSN

2191-1363

Finanzierungs-Informationen

Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.

Page URI

https://pub.uni-bielefeld.de/record/2945870

Zitieren

Schwabedissen J, Glodde T, Vishnevskiy Y, et al. Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants . ChemistryOpen. 2020;9(9):921-928.

Schwabedissen, J., Glodde, T., Vishnevskiy, Y., Stammler, H. - G., Flierl, L., Kornath, A. J., & Mitzel, N. W. (2020). Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants . ChemistryOpen, 9(9), 921-928. https://doi.org/10.1002/open.202000172

Schwabedissen, Jan, Glodde, Timo, Vishnevskiy, Yury, Stammler, Hans-Georg, Flierl, Lukas, Kornath, Andreas J., and Mitzel, Norbert W. 2020. “Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants ”. ChemistryOpen 9 (9): 921-928.

Schwabedissen, J., Glodde, T., Vishnevskiy, Y., Stammler, H. - G., Flierl, L., Kornath, A. J., and Mitzel, N. W. (2020). Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants . ChemistryOpen 9, 921-928.

Schwabedissen, J., et al., 2020. Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants . ChemistryOpen, 9(9), p 921-928.

J. Schwabedissen, et al., “Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants ”, ChemistryOpen, vol. 9, 2020, pp. 921-928.

Schwabedissen, J., Glodde, T., Vishnevskiy, Y., Stammler, H.-G., Flierl, L., Kornath, A.J., Mitzel, N.W.: Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants . ChemistryOpen. 9, 921-928 (2020).

Schwabedissen, Jan, Glodde, Timo, Vishnevskiy, Yury, Stammler, Hans-Georg, Flierl, Lukas, Kornath, Andreas J., and Mitzel, Norbert W. “Structures and Properties of trans‐1,3,3,3‐Tetrafluoro‐ propene (HFO‐1234ze) and 2,3,3,3‐Tetrafluoropropene (HFO‐1234yf) Refrigerants ”. ChemistryOpen 9.9 (2020): 921-928.

Alle Dateien verfügbar unter der/den folgenden Lizenz(en):

Creative Commons Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International (CC BY-NC-ND 4.0):