Heterogeneous Catalysts "on the Move": Flow Chemistry with Fluid Immobilised (Bio)Catalysts

Adebar N, Gröger H (2020)
European Journal of Organic Chemistry.

Zeitschriftenaufsatz | E-Veröff. vor dem Druck | Englisch
 
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Abstract / Bemerkung
As both, continuous synthesis and (bio-)catalysis gained increasing interest in research as well as for industrial applications, ways for merging these fields enables novel opportunities for modern sustainable process development. In this contribution, an alternative approach for the application of immobilized enzymes in continuous flow processes is presented utilizing heterogeneous biocatalysts as a mobile phase. Based on superabsorber-entrapped enzymes and whole cells as a "fluid heterogeneous phase", a segmented hydrogel/organic solvent system was developed. Its applicability was investigated with two entirely different model reaction systems, namely the alcohol dehydrogenase (ADH)-catalysed reduction of acetophenone, and the aldoxime dehydratase (Oxd)-catalysed dehydration of octanal oxime. In particular for solvent labile catalytic systems, this approach offers an alternative for the application of immobilized biocatalysts in a continuously running process beyond the "classic" packed bed and wall coated reactors.
Stichworte
Biocatalysis; Flow chemistry; Heterogenous catalysis; Immobilisation
Erscheinungsjahr
2020
Zeitschriftentitel
European Journal of Organic Chemistry
ISSN
1434-193X
eISSN
1099-0690
Page URI
https://pub.uni-bielefeld.de/record/2945835

Zitieren

Adebar N, Gröger H. Heterogeneous Catalysts "on the Move": Flow Chemistry with Fluid Immobilised (Bio)Catalysts. European Journal of Organic Chemistry. 2020.
Adebar, N., & Gröger, H. (2020). Heterogeneous Catalysts "on the Move": Flow Chemistry with Fluid Immobilised (Bio)Catalysts. European Journal of Organic Chemistry. doi:10.1002/ejoc.202000705
Adebar, N., and Gröger, H. (2020). Heterogeneous Catalysts "on the Move": Flow Chemistry with Fluid Immobilised (Bio)Catalysts. European Journal of Organic Chemistry.
Adebar, N., & Gröger, H., 2020. Heterogeneous Catalysts "on the Move": Flow Chemistry with Fluid Immobilised (Bio)Catalysts. European Journal of Organic Chemistry.
N. Adebar and H. Gröger, “Heterogeneous Catalysts "on the Move": Flow Chemistry with Fluid Immobilised (Bio)Catalysts”, European Journal of Organic Chemistry, 2020.
Adebar, N., Gröger, H.: Heterogeneous Catalysts "on the Move": Flow Chemistry with Fluid Immobilised (Bio)Catalysts. European Journal of Organic Chemistry. (2020).
Adebar, Niklas, and Gröger, Harald. “Heterogeneous Catalysts "on the Move": Flow Chemistry with Fluid Immobilised (Bio)Catalysts”. European Journal of Organic Chemistry (2020).

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