Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex.
Schober L, Sako M, Takizawa S, Gröger H, Sasai H (2020)
Chemical communications (Cambridge, England).
Zeitschriftenaufsatz
| E-Veröff. vor dem Druck | Englisch
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Autor*in
Schober, LukasUniBi;
Sako, Makoto;
Takizawa, Shinobu;
Gröger, HaraldUniBi;
Sasai, Hiroaki
Abstract / Bemerkung
An enantioselective oxa-Piancatelli reaction was established for the first time using a chiral vanadium(v) catalyst. The dual Bronsted and Lewis acid properties of the vanadium catalyst afforded 4-hydroxycyclopent-2-enone derivatives in up to 90% yields and with 93:7 enantiomeric ratios, as well as >20:1 diastereomeric ratios.
Erscheinungsjahr
2020
Zeitschriftentitel
Chemical communications (Cambridge, England)
eISSN
1364-548X
Page URI
https://pub.uni-bielefeld.de/record/2945206
Zitieren
Schober L, Sako M, Takizawa S, Gröger H, Sasai H. Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex. Chemical communications (Cambridge, England). 2020.
Schober, L., Sako, M., Takizawa, S., Gröger, H., & Sasai, H. (2020). Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex. Chemical communications (Cambridge, England). doi:10.1039/d0cc02621b
Schober, Lukas, Sako, Makoto, Takizawa, Shinobu, Gröger, Harald, and Sasai, Hiroaki. 2020. “Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex.”. Chemical communications (Cambridge, England).
Schober, L., Sako, M., Takizawa, S., Gröger, H., and Sasai, H. (2020). Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex. Chemical communications (Cambridge, England).
Schober, L., et al., 2020. Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex. Chemical communications (Cambridge, England).
L. Schober, et al., “Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex.”, Chemical communications (Cambridge, England), 2020.
Schober, L., Sako, M., Takizawa, S., Gröger, H., Sasai, H.: Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex. Chemical communications (Cambridge, England). (2020).
Schober, Lukas, Sako, Makoto, Takizawa, Shinobu, Gröger, Harald, and Sasai, Hiroaki. “Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex.”. Chemical communications (Cambridge, England) (2020).
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