An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair

Holtkamp, Philipp; Glodde, Timo; Poier, Dario; Neumann, Beate; Stammler, Hans-Georg; Mitzel, Norbert W.

An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair

Holtkamp P, Glodde T, Poier D, Neumann B, Stammler H-G, Mitzel NW (2020)
Angewandte Chemie (International ed. in English) 59(40): 17388-17392.

Zeitschriftenaufsatz | Veröffentlicht | Englisch

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DOI

https://doi.org/10.1002/anie.202007653

URN

urn:nbn:de:0070-pub-29443187

Autor*in

Holtkamp, Philipp^UniBi; Glodde, Timo^UniBi; Poier, Dario; Neumann, Beate^UniBi; Stammler, Hans-Georg^UniBi; Mitzel, Norbert W.^UniBi

Einrichtung

Fakultät für Chemie > Anorganische Chemie und Strukturchemie

Abstract / Bemerkung

The geminal frustrated Lewis pair (F5C2)3SnCH2P(tBu)2 (1) reacted with N‐sulfinylaniline PhNSO to afford the first sulfur monoxide adduct of a main group metal, (F5C2)3SnCH2P(tBu)2⋅SO (2), which contains a SnCPSO ring. The second product is a phenylnitrene adduct of 1. The surprising stability of 2 was compared with the stabilities of the so far inaccessible O2 and S2 adducts of 1. Attempts to prepare these from 1 and the elemental chalcogens (O2, S8, Se∞, Te∞) led to four‐membered SnCPE ring systems. Quantum‐chemical investigations of 2 demonstrate the bond polarity of the SO unit to stabilize 2.

Erscheinungsjahr

2020

Zeitschriftentitel

Angewandte Chemie (International ed. in English)

Band

Ausgabe

Seite(n)

17388-17392

Urheberrecht / Lizenzen

Creative Commons Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International (CC BY-NC-ND 4.0)

eISSN

1521-3773

Finanzierungs-Informationen

Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.

Page URI

https://pub.uni-bielefeld.de/record/2944318

Zitieren

Holtkamp P, Glodde T, Poier D, Neumann B, Stammler H-G, Mitzel NW. An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair. Angewandte Chemie (International ed. in English). 2020;59(40):17388-17392.

Holtkamp, P., Glodde, T., Poier, D., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2020). An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair. Angewandte Chemie (International ed. in English), 59(40), 17388-17392. https://doi.org/10.1002/anie.202007653

Holtkamp, Philipp, Glodde, Timo, Poier, Dario, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. 2020. “An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair”. Angewandte Chemie (International ed. in English) 59 (40): 17388-17392.

Holtkamp, P., Glodde, T., Poier, D., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2020). An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair. Angewandte Chemie (International ed. in English) 59, 17388-17392.

Holtkamp, P., et al., 2020. An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair. Angewandte Chemie (International ed. in English), 59(40), p 17388-17392.

P. Holtkamp, et al., “An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair”, Angewandte Chemie (International ed. in English), vol. 59, 2020, pp. 17388-17392.

Holtkamp, P., Glodde, T., Poier, D., Neumann, B., Stammler, H.-G., Mitzel, N.W.: An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair. Angewandte Chemie (International ed. in English). 59, 17388-17392 (2020).

Holtkamp, Philipp, Glodde, Timo, Poier, Dario, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair”. Angewandte Chemie (International ed. in English) 59.40 (2020): 17388-17392.

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