Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate

Tiessen, Natalia; Neumann, Beate; Stammler, Hans-Georg; Hoge, Berthold

Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate

Tiessen N, Neumann B, Stammler H-G, Hoge B (2020)
Chemistry - A European journal 26(60): 13611-13614.

Zeitschriftenaufsatz | Veröffentlicht | Englisch

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DOI

https://doi.org/10.1002/chem.202000668

URN

urn:nbn:de:0070-pub-29427547

Autor*in

Tiessen, Natalia^UniBi; Neumann, Beate^UniBi; Stammler, Hans-Georg^UniBi; Hoge, Berthold^UniBi

Einrichtung

Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Fakultät für Chemie > Anorganische Chemie II

Abstract / Bemerkung

While perfluorinated aryl, aryloxy and alkoxy aluminum species are well-established as weakly coordinating anions (WCAs), corresponding perfluoroalkyl aluminum derivatives are virtually unknown. Reaction of Si(C 2 F 5 ) 3 CH 3 with Li[AlH 4 ] afforded the tetrakis(pentafluoroethyl)aluminate, [ Al(C 2 F 5 ) 4 ] - . Several salts of the [ Al(C 2 F 5 ) 4 ] - ion were synthesized and characterized by NMR spectroscopic methods, mass spectrometry, X-ray diffraction studies and elemental analysis. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Erscheinungsjahr

2020

Zeitschriftentitel

Chemistry - A European journal

Band

Ausgabe

Seite(n)

13611-13614

Urheberrecht / Lizenzen

Creative Commons Namensnennung 4.0 International Public License (CC-BY 4.0)

eISSN

1521-3765

Finanzierungs-Informationen

Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.

Page URI

https://pub.uni-bielefeld.de/record/2942754

Zitieren

Tiessen N, Neumann B, Stammler H-G, Hoge B. Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal. 2020;26(60):13611-13614.

Tiessen, N., Neumann, B., Stammler, H. - G., & Hoge, B. (2020). Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal, 26(60), 13611-13614. https://doi.org/10.1002/chem.202000668

Tiessen, Natalia, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. 2020. “Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate”. Chemistry - A European journal 26 (60): 13611-13614.

Tiessen, N., Neumann, B., Stammler, H. - G., and Hoge, B. (2020). Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal 26, 13611-13614.

Tiessen, N., et al., 2020. Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal, 26(60), p 13611-13614.

N. Tiessen, et al., “Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate”, Chemistry - A European journal, vol. 26, 2020, pp. 13611-13614.

Tiessen, N., Neumann, B., Stammler, H.-G., Hoge, B.: Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal. 26, 13611-13614 (2020).

Tiessen, Natalia, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate”. Chemistry - A European journal 26.60 (2020): 13611-13614.

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