Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate.

Tiessen N, Neumann B, Stammler H-G, Hoge B (2020)
Chemistry - A European journal 26(60): 13611-13614.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
While perfluorinated aryl, aryloxy and alkoxy aluminum species are well-established as weakly coordinating anions (WCAs), corresponding perfluoroalkyl aluminum derivatives are virtually unknown. Reaction of Si(C 2 F 5 ) 3 CH 3 with Li[AlH 4 ] afforded the tetrakis(pentafluoroethyl)aluminate, [ Al(C 2 F 5 ) 4 ] - . Several salts of the [ Al(C 2 F 5 ) 4 ] - ion were synthesized and characterized by NMR spectroscopic methods, mass spectrometry, X-ray diffraction studies and elemental analysis. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Erscheinungsjahr
2020
Zeitschriftentitel
Chemistry - A European journal
Band
26
Ausgabe
60
Seite(n)
13611-13614
eISSN
1521-3765
Finanzierungs-Informationen
Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.
Page URI
https://pub.uni-bielefeld.de/record/2942754

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Tiessen N, Neumann B, Stammler H-G, Hoge B. Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal. 2020;26(60):13611-13614.
Tiessen, N., Neumann, B., Stammler, H. - G., & Hoge, B. (2020). Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal, 26(60), 13611-13614. doi:10.1002/chem.202000668
Tiessen, N., Neumann, B., Stammler, H. - G., and Hoge, B. (2020). Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal 26, 13611-13614.
Tiessen, N., et al., 2020. Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal, 26(60), p 13611-13614.
N. Tiessen, et al., “Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate.”, Chemistry - A European journal, vol. 26, 2020, pp. 13611-13614.
Tiessen, N., Neumann, B., Stammler, H.-G., Hoge, B.: Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate. Chemistry - A European journal. 26, 13611-13614 (2020).
Tiessen, Natalia, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Synthesis and Characterization of the Tetrakis(pentafluoroethyl)aluminate.”. Chemistry - A European journal 26.60 (2020): 13611-13614.
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2020-11-04T10:47:38Z
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