Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene

Nishiuchi T, Ito R, Stratmann E, Kubo T (2020)
JOURNAL OF ORGANIC CHEMISTRY 85(1): 179-186.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Nishiuchi, Tomohiko; Ito, Ryuoh; Stratmann, ErikUniBi; Kubo, Takashi
Abstract / Bemerkung
We prepared a new overcrowded tristricyclic aromatic ene (TAE) and investigated its external stimuli-responsive behavior for the switching between a closed-shell folded form and an open-shell twisted form. Upon photoirradiation, the folded form transforms into the biradical twisted form, whereas by keeping the twisted form in the dark, the reverse reaction gradually occurs at room temperature. This switchable conformational change is analyzed by means of UV-vis and electron spin resonance spectroscopies, cyclic voltammetry, density functional theory calculations, and kinetic studies.
Erscheinungsjahr
2020
Zeitschriftentitel
JOURNAL OF ORGANIC CHEMISTRY
Band
85
Ausgabe
1
Seite(n)
179-186
ISSN
0022-3263
eISSN
1520-6904
Page URI
https://pub.uni-bielefeld.de/record/2940706

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Nishiuchi T, Ito R, Stratmann E, Kubo T. Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene. JOURNAL OF ORGANIC CHEMISTRY. 2020;85(1):179-186.
Nishiuchi, T., Ito, R., Stratmann, E., & Kubo, T. (2020). Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene. JOURNAL OF ORGANIC CHEMISTRY, 85(1), 179-186. doi:10.1021/acs.joc.9b02432
Nishiuchi, T., Ito, R., Stratmann, E., and Kubo, T. (2020). Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene. JOURNAL OF ORGANIC CHEMISTRY 85, 179-186.
Nishiuchi, T., et al., 2020. Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene. JOURNAL OF ORGANIC CHEMISTRY, 85(1), p 179-186.
T. Nishiuchi, et al., “Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene”, JOURNAL OF ORGANIC CHEMISTRY, vol. 85, 2020, pp. 179-186.
Nishiuchi, T., Ito, R., Stratmann, E., Kubo, T.: Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene. JOURNAL OF ORGANIC CHEMISTRY. 85, 179-186 (2020).
Nishiuchi, Tomohiko, Ito, Ryuoh, Stratmann, Erik, and Kubo, Takashi. “Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene”. JOURNAL OF ORGANIC CHEMISTRY 85.1 (2020): 179-186.

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