A crystalline C5-protonated 1,3-imidazol-4-ylidene.

Rottschäfer, Dennis; Glodde, Timo; Neumann, Beate; Stammler, Hans-Georg; Ghadwal, Rajendra

A crystalline C5-protonated 1,3-imidazol-4-ylidene.

Rottschäfer D, Glodde T, Neumann B, Stammler H-G, Ghadwal R (2020)
Chemical communications (Cambridge, England) 56(13): 2027-2030.

Zeitschriftenaufsatz | Veröffentlicht | Englisch

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DOI

https://doi.org/10.1039/c9cc09428h

Autor*in

Rottschäfer, Dennis^UniBi; Glodde, Timo^UniBi; Neumann, Beate^UniBi; Stammler, Hans-Georg^UniBi; Ghadwal, Rajendra^UniBi

Einrichtung

Fakultät für Chemie > Anorganische Chemie und Strukturchemie

Abstract / Bemerkung

The first C5-protonated 1,3-imidazol-based mesoionic carbene iMICBp (2) (iMICBp = :C{CH(NDipp)2C(Bp)}; Dipp = 2,6-iPr2C6H3; Bp = 4-PhC6H4) has been reported as a crystalline solid. Spectroscopic, X-ray diffraction, and computational studies clearly support the carbenic nature of 2, which has been further corroborated by its reactions with Ni(CO)4, (Me2S)AuCl, white phosphorus, and CO2.

Erscheinungsjahr

2020

Zeitschriftentitel

Chemical communications (Cambridge, England)

Band

Ausgabe

Seite(n)

2027-2030

ISSN

1364-548X

Page URI

https://pub.uni-bielefeld.de/record/2940374

Zitieren

Rottschäfer D, Glodde T, Neumann B, Stammler H-G, Ghadwal R. A crystalline C5-protonated 1,3-imidazol-4-ylidene. Chemical communications (Cambridge, England). 2020;56(13):2027-2030.

Rottschäfer, D., Glodde, T., Neumann, B., Stammler, H. - G., & Ghadwal, R. (2020). A crystalline C5-protonated 1,3-imidazol-4-ylidene. Chemical communications (Cambridge, England), 56(13), 2027-2030. https://doi.org/10.1039/c9cc09428h

Rottschäfer, Dennis, Glodde, Timo, Neumann, Beate, Stammler, Hans-Georg, and Ghadwal, Rajendra. 2020. “A crystalline C5-protonated 1,3-imidazol-4-ylidene.”. Chemical communications (Cambridge, England) 56 (13): 2027-2030.

Rottschäfer, D., Glodde, T., Neumann, B., Stammler, H. - G., and Ghadwal, R. (2020). A crystalline C5-protonated 1,3-imidazol-4-ylidene. Chemical communications (Cambridge, England) 56, 2027-2030.

Rottschäfer, D., et al., 2020. A crystalline C5-protonated 1,3-imidazol-4-ylidene. Chemical communications (Cambridge, England), 56(13), p 2027-2030.

D. Rottschäfer, et al., “A crystalline C5-protonated 1,3-imidazol-4-ylidene.”, Chemical communications (Cambridge, England), vol. 56, 2020, pp. 2027-2030.

Rottschäfer, D., Glodde, T., Neumann, B., Stammler, H.-G., Ghadwal, R.: A crystalline C5-protonated 1,3-imidazol-4-ylidene. Chemical communications (Cambridge, England). 56, 2027-2030 (2020).

Rottschäfer, Dennis, Glodde, Timo, Neumann, Beate, Stammler, Hans-Georg, and Ghadwal, Rajendra. “A crystalline C5-protonated 1,3-imidazol-4-ylidene.”. Chemical communications (Cambridge, England) 56.13 (2020): 2027-2030.

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