Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom.

Sharma MK, Neumann B, Stammler H-G, Andrada DM, Ghadwal R (2019)
Chemical communications.

Zeitschriftenaufsatz | Veröffentlicht| Englisch
 
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Abstract / Bemerkung
The first terminal arsinidene complexes [{(NHC)C(Ph)}As]Fe(CO)4 (NHC = IPr = C{(NDipp)CH}2 5, Me-IPr = C{(NDipp)CMe}2 6; Dipp = 2,6-iPr2C6H3) with a two-coordinated arsenic atom have been reported as crystalline solids. Calculations suggest that 5 and 6 are electrophilic, which has been demonstrated by the reaction of 5 with an NHC nucleophile (IMe4), affording the Lewis adduct [{(IPr)C(Ph)}As(IMe4)]Fe(CO)4 (7) (IMe4 = C(NMeCMe)2).
Erscheinungsjahr
2019
Zeitschriftentitel
Chemical communications
eISSN
1364-548X
Page URI
https://pub.uni-bielefeld.de/record/2939277

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Sharma MK, Neumann B, Stammler H-G, Andrada DM, Ghadwal R. Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications. 2019.
Sharma, M. K., Neumann, B., Stammler, H. - G., Andrada, D. M., & Ghadwal, R. (2019). Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications. doi:10.1039/c9cc08630g
Sharma, M. K., Neumann, B., Stammler, H. - G., Andrada, D. M., and Ghadwal, R. (2019). Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications.
Sharma, M.K., et al., 2019. Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications.
M.K. Sharma, et al., “Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom.”, Chemical communications, 2019.
Sharma, M.K., Neumann, B., Stammler, H.-G., Andrada, D.M., Ghadwal, R.: Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications. (2019).
Sharma, Mahendra Kumar, Neumann, Beate, Stammler, Hans-Georg, Andrada, Diego M., and Ghadwal, Rajendra. “Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom.”. Chemical communications (2019).

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