Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom.
Sharma MK, Neumann B, Stammler H-G, Andrada DM, Ghadwal R (2019)
Chemical communications 55(97): 14669-14672.
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Autor*in
Sharma, Mahendra KumarUniBi;
Neumann, BeateUniBi;
Stammler, Hans-GeorgUniBi;
Andrada, Diego M.;
Ghadwal, RajendraUniBi 
Abstract / Bemerkung
The first terminal arsinidene complexes [{(NHC)C(Ph)}As]Fe(CO)4 (NHC = IPr = C{(NDipp)CH}2 5, Me-IPr = C{(NDipp)CMe}2 6; Dipp = 2,6-iPr2C6H3) with a two-coordinated arsenic atom have been reported as crystalline solids. Calculations suggest that 5 and 6 are electrophilic, which has been demonstrated by the reaction of 5 with an NHC nucleophile (IMe4), affording the Lewis adduct [{(IPr)C(Ph)}As(IMe4)]Fe(CO)4 (7) (IMe4 = C(NMeCMe)2).
Erscheinungsjahr
2019
Zeitschriftentitel
Chemical communications
Band
55
Ausgabe
97
Seite(n)
14669-14672
ISSN
1359-7345
eISSN
1364-548X
Page URI
https://pub.uni-bielefeld.de/record/2939277
Zitieren
Sharma MK, Neumann B, Stammler H-G, Andrada DM, Ghadwal R. Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications. 2019;55(97):14669-14672.
Sharma, M. K., Neumann, B., Stammler, H. - G., Andrada, D. M., & Ghadwal, R. (2019). Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications, 55(97), 14669-14672. doi:10.1039/c9cc08630g
Sharma, Mahendra Kumar, Neumann, Beate, Stammler, Hans-Georg, Andrada, Diego M., and Ghadwal, Rajendra. 2019. “Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom.”. Chemical communications 55 (97): 14669-14672.
Sharma, M. K., Neumann, B., Stammler, H. - G., Andrada, D. M., and Ghadwal, R. (2019). Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications 55, 14669-14672.
Sharma, M.K., et al., 2019. Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications, 55(97), p 14669-14672.
M.K. Sharma, et al., “Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom.”, Chemical communications, vol. 55, 2019, pp. 14669-14672.
Sharma, M.K., Neumann, B., Stammler, H.-G., Andrada, D.M., Ghadwal, R.: Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom. Chemical communications. 55, 14669-14672 (2019).
Sharma, Mahendra Kumar, Neumann, Beate, Stammler, Hans-Georg, Andrada, Diego M., and Ghadwal, Rajendra. “Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom.”. Chemical communications 55.97 (2019): 14669-14672.
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