Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates
Reichel M, Krumm B, Vishnevskiy Y, Blomeyer S, Schwabedissen J, Stammler H-G, Karaghiosoff K, Mitzel NW (2019)
Angewandte Chemie (International ed. in English) 58(51): 18557-18561.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Autor*in
Reichel, Marco;
Krumm, Burkhard;
Vishnevskiy, YuryUniBi;
Blomeyer, SebastianUniBi 
;
Schwabedissen, JanUniBi;
Stammler, Hans-GeorgUniBi;
Karaghiosoff, Konstantin;
Mitzel, Norbert W.UniBi
;
Schwabedissen, JanUniBi;
Stammler, Hans-GeorgUniBi;
Karaghiosoff, Konstantin;
Mitzel, Norbert W.UniBiAbstract / Bemerkung
An improved synthesis of the simplest nitric acid ester, methyl nitrate, and a new synthesis of fluoromethyl nitrate use the metathesis of the corresponding iodomethanes with silver nitrate. Both compounds were identified by spectroscopy and the structures determined for in situ grown crystals by X-ray diffraction as well as in the gas phase by electron diffraction. Fluorination leads to structures with shorter C-O and N-O bonds, has an energetically destabilizing effect and increases friction sensitivity, but decreases detonation performance. © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
Erscheinungsjahr
2019
Zeitschriftentitel
Angewandte Chemie (International ed. in English)
Band
58
Ausgabe
51
Seite(n)
18557-18561
Urheberrecht / Lizenzen
ISSN
1433-7851
eISSN
1521-3773
Finanzierungs-Informationen
Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.
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https://pub.uni-bielefeld.de/record/2939039
Zitieren
Reichel M, Krumm B, Vishnevskiy Y, et al. Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English). 2019;58(51):18557-18561.
Reichel, M., Krumm, B., Vishnevskiy, Y., Blomeyer, S., Schwabedissen, J., Stammler, H. - G., Karaghiosoff, K., et al. (2019). Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English), 58(51), 18557-18561. doi:10.1002/anie.201911300
Reichel, Marco, Krumm, Burkhard, Vishnevskiy, Yury, Blomeyer, Sebastian, Schwabedissen, Jan, Stammler, Hans-Georg, Karaghiosoff, Konstantin, and Mitzel, Norbert W. 2019. “Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates”. Angewandte Chemie (International ed. in English) 58 (51): 18557-18561.
Reichel, M., Krumm, B., Vishnevskiy, Y., Blomeyer, S., Schwabedissen, J., Stammler, H. - G., Karaghiosoff, K., and Mitzel, N. W. (2019). Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English) 58, 18557-18561.
Reichel, M., et al., 2019. Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English), 58(51), p 18557-18561.
M. Reichel, et al., “Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates”, Angewandte Chemie (International ed. in English), vol. 58, 2019, pp. 18557-18561.
Reichel, M., Krumm, B., Vishnevskiy, Y., Blomeyer, S., Schwabedissen, J., Stammler, H.-G., Karaghiosoff, K., Mitzel, N.W.: Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English). 58, 18557-18561 (2019).
Reichel, Marco, Krumm, Burkhard, Vishnevskiy, Yury, Blomeyer, Sebastian, Schwabedissen, Jan, Stammler, Hans-Georg, Karaghiosoff, Konstantin, and Mitzel, Norbert W. “Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates”. Angewandte Chemie (International ed. in English) 58.51 (2019): 18557-18561.
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