Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates

Reichel M, Krumm B, Vishnevskiy Y, Blomeyer S, Schwabedissen J, Stammler H-G, Karaghiosoff K, Mitzel NW (2019)
Angewandte Chemie (International ed. in English) 58(51): 18557-18561.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
OA 1.76 MB
Autor*in
Abstract / Bemerkung
An improved synthesis of the simplest nitric acid ester, methyl nitrate, and a new synthesis of fluoromethyl nitrate use the metathesis of the corresponding iodomethanes with silver nitrate. Both compounds were identified by spectroscopy and the structures determined for in situ grown crystals by X-ray diffraction as well as in the gas phase by electron diffraction. Fluorination leads to structures with shorter C-O and N-O bonds, has an energetically destabilizing effect and increases friction sensitivity, but decreases detonation performance. © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
Erscheinungsjahr
2019
Zeitschriftentitel
Angewandte Chemie (International ed. in English)
Band
58
Ausgabe
51
Seite(n)
18557-18561
ISSN
1433-7851
eISSN
1521-3773
Page URI
https://pub.uni-bielefeld.de/record/2939039

Zitieren

Reichel M, Krumm B, Vishnevskiy Y, et al. Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English). 2019;58(51):18557-18561.
Reichel, M., Krumm, B., Vishnevskiy, Y., Blomeyer, S., Schwabedissen, J., Stammler, H. - G., Karaghiosoff, K., et al. (2019). Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English), 58(51), 18557-18561. doi:10.1002/anie.201911300
Reichel, M., Krumm, B., Vishnevskiy, Y., Blomeyer, S., Schwabedissen, J., Stammler, H. - G., Karaghiosoff, K., and Mitzel, N. W. (2019). Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English) 58, 18557-18561.
Reichel, M., et al., 2019. Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English), 58(51), p 18557-18561.
M. Reichel, et al., “Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates”, Angewandte Chemie (International ed. in English), vol. 58, 2019, pp. 18557-18561.
Reichel, M., Krumm, B., Vishnevskiy, Y., Blomeyer, S., Schwabedissen, J., Stammler, H.-G., Karaghiosoff, K., Mitzel, N.W.: Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English). 58, 18557-18561 (2019).
Reichel, Marco, Krumm, Burkhard, Vishnevskiy, Yury, Blomeyer, Sebastian, Schwabedissen, Jan, Stammler, Hans-Georg, Karaghiosoff, Konstantin, and Mitzel, Norbert W. “Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates”. Angewandte Chemie (International ed. in English) 58.51 (2019): 18557-18561.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Creative Commons Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International (CC BY-NC-ND 4.0):
Volltext(e)
Access Level
OA Open Access
Zuletzt Hochgeladen
2020-03-13T12:42:07Z
MD5 Prüfsumme
78978d175f95290a9657937050938705

Link(s) zu Volltext(en)
Access Level
OA Open Access

Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®

Quellen

PMID: 31573130
PubMed | Europe PMC

Suchen in

Google Scholar