Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates.

Reichel M, Krumm B, Vishnevskiy Y, Blomeyer S, Schwabedissen J, Stammler H-G, Karaghiosoff K, Mitzel NW (2019)
Angewandte Chemie (International ed. in English).

Zeitschriftenaufsatz | E-Veröff. vor dem Druck| Englisch
 
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Abstract / Bemerkung
An improved synthesis of the simplest nitric acid ester, methyl nitrate, and a new synthesis of fluoromethyl nitrate use the metathesis of the corresponding iodomethanes with silver nitrate. Both compounds were identified by spectroscopy and the structures determined for in situ grown crystals by X-ray diffraction as well as in the gas phase by electron diffraction. Fluorination leads to structures with shorter C-O and N-O bonds, has an energetically destabilizing effect and increases friction sensitivity, but decreases detonation performance. © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
Erscheinungsjahr
2019
Zeitschriftentitel
Angewandte Chemie (International ed. in English)
ISSN
1521-3773
Page URI
https://pub.uni-bielefeld.de/record/2939039

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Reichel M, Krumm B, Vishnevskiy Y, et al. Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English). 2019.
Reichel, M., Krumm, B., Vishnevskiy, Y., Blomeyer, S., Schwabedissen, J., Stammler, H. - G., Karaghiosoff, K., et al. (2019). Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English). doi:10.1002/anie.201911300
Reichel, M., Krumm, B., Vishnevskiy, Y., Blomeyer, S., Schwabedissen, J., Stammler, H. - G., Karaghiosoff, K., and Mitzel, N. W. (2019). Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English).
Reichel, M., et al., 2019. Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English).
M. Reichel, et al., “Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates.”, Angewandte Chemie (International ed. in English), 2019.
Reichel, M., Krumm, B., Vishnevskiy, Y., Blomeyer, S., Schwabedissen, J., Stammler, H.-G., Karaghiosoff, K., Mitzel, N.W.: Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English). (2019).
Reichel, Marco, Krumm, Burkhard, Vishnevskiy, Yury, Blomeyer, Sebastian, Schwabedissen, Jan, Stammler, Hans-Georg, Karaghiosoff, Konstantin, and Mitzel, Norbert W. “Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates.”. Angewandte Chemie (International ed. in English) (2019).

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