A Chemiluminescent Metal-Organic Framework

Ruehle B, Virmani E, Engelke H, Hinterholzinger FM, von Zons T, Brosent B, Bein T, Godt A, Wuttke S (2019)
CHEMISTRY-A EUROPEAN JOURNAL 25(25): 6349-6354.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The synthesis and characterization of a chemiluminescent metal-organic framework with high porosity is reported. It consists of Zr6O6(OH)(4) nodes connected by 4,4'(anthracene-9,10-diyl) dibenzoate as the linker and luminophore. It shows the topology known for UiO-66 and is therefore denoted PAP-UiO. The MOF was not only obtained as bulk material but also as a thin film. Exposure of PAP-UiO as bulk or film to a mixture of bis-(2,4,6-trichlorophenyl) oxa-late, hydrogen peroxide, and sodium salicylate in a mixture of dimethyl and dibutyl phthalate evoked strong and long lasting chemiluminescence of the PAP-UiO crystals. Time dependent fluorescence spectroscopy on bulk PAP-UiO and, for comparison, on dimethyl 4,4'-(anthracene-9,10-diyl) dibenzoate provided evidence that the chemiluminescence originates from luminophores being part of the PAP-UiO, including the luminophores inside the crystals.
Erscheinungsjahr
Zeitschriftentitel
CHEMISTRY-A EUROPEAN JOURNAL
Band
25
Ausgabe
25
Seite(n)
6349-6354
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Ruehle B, Virmani E, Engelke H, et al. A Chemiluminescent Metal-Organic Framework. CHEMISTRY-A EUROPEAN JOURNAL. 2019;25(25):6349-6354.
Ruehle, B., Virmani, E., Engelke, H., Hinterholzinger, F. M., von Zons, T., Brosent, B., Bein, T., et al. (2019). A Chemiluminescent Metal-Organic Framework. CHEMISTRY-A EUROPEAN JOURNAL, 25(25), 6349-6354. doi:10.1002/chem.201806041
Ruehle, B., Virmani, E., Engelke, H., Hinterholzinger, F. M., von Zons, T., Brosent, B., Bein, T., Godt, A., and Wuttke, S. (2019). A Chemiluminescent Metal-Organic Framework. CHEMISTRY-A EUROPEAN JOURNAL 25, 6349-6354.
Ruehle, B., et al., 2019. A Chemiluminescent Metal-Organic Framework. CHEMISTRY-A EUROPEAN JOURNAL, 25(25), p 6349-6354.
B. Ruehle, et al., “A Chemiluminescent Metal-Organic Framework”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 25, 2019, pp. 6349-6354.
Ruehle, B., Virmani, E., Engelke, H., Hinterholzinger, F.M., von Zons, T., Brosent, B., Bein, T., Godt, A., Wuttke, S.: A Chemiluminescent Metal-Organic Framework. CHEMISTRY-A EUROPEAN JOURNAL. 25, 6349-6354 (2019).
Ruehle, Bastian, Virmani, Erika, Engelke, Hanna, Hinterholzinger, Florian M., von Zons, Tobias, Brosent, Birte, Bein, Thomas, Godt, Adelheid, and Wuttke, Stefan. “A Chemiluminescent Metal-Organic Framework”. CHEMISTRY-A EUROPEAN JOURNAL 25.25 (2019): 6349-6354.

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