Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes.

Weisheim E, Weigel S, Neumann B, Stammler H-G, Mitzel NW (2019)
Chemical communications 55: 4985-4988.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
All-cis-1,3,5-triethynyl-1,3,5-triorganyl-1,3,5-trisilacyclohexanes (organyl R = Me, Ph) offer flexible scaffolds with three concordantly oriented ethynyl groups. Lithiation with n-BuLi affords the dimeric {[CH2Si(R)(C2Li)]3(THF)3}2 with a drum-like structure in high yields. They can be transformed into other trinuclear organometallic derivatives like the trimercury cage species [CH2Si(R)C2HgC2(R)SiCH2]3.
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Chemical communications
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55
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4985-4988
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Weisheim E, Weigel S, Neumann B, Stammler H-G, Mitzel NW. Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes. Chemical communications . 2019;55:4985-4988.
Weisheim, E., Weigel, S., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2019). Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes. Chemical communications , 55, 4985-4988. doi:10.1039/c9cc02315a
Weisheim, E., Weigel, S., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2019). Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes. Chemical communications 55, 4985-4988.
Weisheim, E., et al., 2019. Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes. Chemical communications , 55, p 4985-4988.
E. Weisheim, et al., “Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes.”, Chemical communications , vol. 55, 2019, pp. 4985-4988.
Weisheim, E., Weigel, S., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes. Chemical communications . 55, 4985-4988 (2019).
Weisheim, Eugen, Weigel, Simon, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Trifunctional organometallic frameworks and cages based on all-cis-1,3,5-triethynyl-1,3,5-trisilacyclohexanes.”. Chemical communications 55 (2019): 4985-4988.

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