A Rational Approach to Tetra-Functional Photo-Switches.

Niermeier P, Lamm J-H, Mix A, Neumann B, Stammler H-G, Mitzel NW (2019)
ChemistryOpen 8(3): 304-315.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
alpha,omega-Bis(1,8-dichloroanthracen-10-yl)alkanes with (CH2) n -linker units (n=1-4) were synthesized starting from 1,8-dichloroanthracen-10(9H)-one. This was transformed into anthracenes with allyl, bromomethyl and propargyl substituents in position 10; these were converted in various C-C-bond formation reactions (plus hydrogenation), leading to two anthracene units flexibly linked by alpha,omega-alkandiyl groups. 1,2-Ethandiyl- and 1,3-propandiyl-linked derivatives were functionalized with ethynyl groups in positions 1, 8, 1' and 8', and these terminally functionalized by Me3Sn groups using Me2NSnMe3. All linked bisanthracenes were subjected to UV light induced cyclomerization and a series of 9,10:9',10'-photo-cyclomers were obtained. Their thermal cycloreversion and (repeated) switchability was demonstrated. 1,3-Bis{1,8-bis[(trimethylstannyl)ethynyl]anthracen-10-yl}propane served as model compound for photo-switchable acceptor molecules and its open and closed forms were characterized by NMR and DOSY experiments.
Erscheinungsjahr
2019
Zeitschriftentitel
ChemistryOpen
Band
8
Ausgabe
3
Seite(n)
304-315
ISSN
2191-1363
eISSN
2191-1363
Finanzierungs-Informationen
Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.
Page URI
https://pub.uni-bielefeld.de/record/2934551

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Niermeier P, Lamm J-H, Mix A, Neumann B, Stammler H-G, Mitzel NW. A Rational Approach to Tetra-Functional Photo-Switches. ChemistryOpen. 2019;8(3):304-315.
Niermeier, P., Lamm, J. - H., Mix, A., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2019). A Rational Approach to Tetra-Functional Photo-Switches. ChemistryOpen, 8(3), 304-315. doi:10.1002/open.201900029
Niermeier, Philipp, Lamm, Jan-Hendrik, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. 2019. “A Rational Approach to Tetra-Functional Photo-Switches.”. ChemistryOpen 8 (3): 304-315.
Niermeier, P., Lamm, J. - H., Mix, A., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2019). A Rational Approach to Tetra-Functional Photo-Switches. ChemistryOpen 8, 304-315.
Niermeier, P., et al., 2019. A Rational Approach to Tetra-Functional Photo-Switches. ChemistryOpen, 8(3), p 304-315.
P. Niermeier, et al., “A Rational Approach to Tetra-Functional Photo-Switches.”, ChemistryOpen, vol. 8, 2019, pp. 304-315.
Niermeier, P., Lamm, J.-H., Mix, A., Neumann, B., Stammler, H.-G., Mitzel, N.W.: A Rational Approach to Tetra-Functional Photo-Switches. ChemistryOpen. 8, 304-315 (2019).
Niermeier, Philipp, Lamm, Jan-Hendrik, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “A Rational Approach to Tetra-Functional Photo-Switches.”. ChemistryOpen 8.3 (2019): 304-315.
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Daten bereitgestellt von Europe PubMed Central.

60 References

Daten bereitgestellt von Europe PubMed Central.


AUTHOR UNKNOWN, 0
Molecular architectures of multi-anthracene assemblies.
Yoshizawa M, Klosterman JK., Chem Soc Rev 43(6), 2014
PMID: 24169958

AUTHOR UNKNOWN, 2004

AUTHOR UNKNOWN, 2012

AUTHOR UNKNOWN, 2007
Synthesis of anthracene-stacked oligomers and polymer.
Morisaki Y, Sawamura T, Murakami T, Chujo Y., Org. Lett. 12(14), 2010
PMID: 20545358

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 1989
Intramolecular triplet energy transfer in anthracene-based platinum acetylide oligomers.
Li Y, Kose ME, Schanze KS., J Phys Chem B 117(30), 2013
PMID: 23819772
Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone.
Chmiel J, Neumann B, Stammler HG, Mitzel NW., Chemistry 16(39), 2010
PMID: 20827789

AUTHOR UNKNOWN, 2014

AUTHOR UNKNOWN, 2014

AUTHOR UNKNOWN, 2000

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 1978
Polyalkynylanthracenes--syntheses, structures and their behaviour towards UV irradiation.
Lamm JH, Glatthor J, Weddeling JH, Mix A, Chmiel J, Neumann B, Stammler HG, Mitzel NW., Org. Biomol. Chem. 12(37), 2014
PMID: 25162922

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 1966

AUTHOR UNKNOWN, 1971

AUTHOR UNKNOWN, 1992

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 1984

AUTHOR UNKNOWN, 1987
Reversible trapping and reaction acceleration within dynamically self-assembling nanoflasks.
Zhao H, Sen S, Udayabhaskararao T, Sawczyk M, Kucanda K, Manna D, Kundu PK, Lee JW, Kral P, Klajn R., Nat Nanotechnol 11(1), 2015
PMID: 26595335

AUTHOR UNKNOWN, 1993

AUTHOR UNKNOWN, 1955

AUTHOR UNKNOWN, 1989

AUTHOR UNKNOWN, 2018

AUTHOR UNKNOWN, 1999

AUTHOR UNKNOWN, 2013

AUTHOR UNKNOWN, 1975

AUTHOR UNKNOWN, 1980

AUTHOR UNKNOWN, 2014

AUTHOR UNKNOWN, 2007

AUTHOR UNKNOWN, 2007

AUTHOR UNKNOWN, 2018

AUTHOR UNKNOWN, 1993

AUTHOR UNKNOWN, 1978
Covalent radii revisited.
Cordero B, Gomez V, Platero-Prats AE, Reves M, Echeverria J, Cremades E, Barragan F, Alvarez S., Dalton Trans (21), 2008
PMID: 18478144
Intramolecular London Dispersion Interaction Effects on Gas-Phase and Solid-State Structures of Diamondoid Dimers.
Fokin AA, Zhuk TS, Blomeyer S, Perez C, Chernish LV, Pashenko AE, Antony J, Vishnevskiy YV, Berger RJF, Grimme S, Logemann C, Schnell M, Mitzel NW, Schreiner PR., J. Am. Chem. Soc. 139(46), 2017
PMID: 29037036

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 1999

AUTHOR UNKNOWN, 0
Determining accurate molecular sizes in solution through NMR diffusion spectroscopy.
Macchioni A, Ciancaleoni G, Zuccaccia C, Zuccaccia D., Chem Soc Rev 37(3), 2007
PMID: 18224258
Characterization of reactive intermediates by multinuclear diffusion-ordered NMR spectroscopy (DOSY).
Li D, Keresztes I, Hopson R, Williard PG., Acc. Chem. Res. 42(2), 2009
PMID: 19105594

AUTHOR UNKNOWN, 0
Tridentate Lewis Acids Based on 1,3,5-Trisilacyclohexane Backbones and an Example of Their Host-Guest Chemistry.
Weisheim E, Reuter CG, Heinrichs P, Vishnevskiy YV, Mix A, Neumann B, Stammler HG, Mitzel NW., Chemistry 21(35), 2015
PMID: 26213228
Tridentate Lewis-acids based on triphenylsilane.
Tomaschautzky J, Neumann B, Stammler HG, Mix A, Mitzel NW., Dalton Trans 46(5), 2017
PMID: 28098286

AUTHOR UNKNOWN, 2019

AUTHOR UNKNOWN, 2018

AUTHOR UNKNOWN, 2009

AUTHOR UNKNOWN, 2015
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