Trefoil-Shaped Porous Nanographenes Bearing a Tribenzotriquinacene Core by Three-fold Scholl Macrocyclization

He L, Ng C-F, Li Y, Liu Z, Kuck D, Chow H-F (2018)
Angewandte Chemie International Edition 57(41): 13635-13639.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
He, Lisi; Ng, Chun-Fai; Li, Yuke; Liu, Zhifeng; Kuck, DietmarUniBi; Chow, Hak-Fun
Abstract / Bemerkung
Porous curved polycyclic aromatic compounds 6 and 14 bearing a tribenzotriquinacene (TBTQ) core encircled by an m,p,p,m,m,p,p,m,m,p,p,m-cyclododecaphenylene belt were synthesized and characterized by NMR spectroscopy and mass spectrometry. These trefoil hydrocarbon macrocycles were constructed in high yield using an intramolecular threefold Scholl macrocyclization. X-ray crystal analysis of 14 demonstrated a large wizard-hat-shaped structure with three pores (radii 2.9-3.0 angstrom). The pi-stacking aggregation of the hexa-n-dodecyloxy derivative 6a and the chloride anion binding properties of 14 were studied by NMR spectroscopy. Such stacking and anion binding properties were much weaker in the singly 11 and doubly macrocyclized products 12.
Stichworte
macrocycles; polycyclic aromatic compounds; porous curved nanographene; Scholl cyclization; tribenzotriquinacene
Erscheinungsjahr
2018
Zeitschriftentitel
Angewandte Chemie International Edition
Band
57
Ausgabe
41
Seite(n)
13635-13639
ISSN
1433-7851
eISSN
1521-3773
Page URI
https://pub.uni-bielefeld.de/record/2931979

Zitieren

He L, Ng C-F, Li Y, Liu Z, Kuck D, Chow H-F. Trefoil-Shaped Porous Nanographenes Bearing a Tribenzotriquinacene Core by Three-fold Scholl Macrocyclization. Angewandte Chemie International Edition. 2018;57(41):13635-13639.
He, L., Ng, C. - F., Li, Y., Liu, Z., Kuck, D., & Chow, H. - F. (2018). Trefoil-Shaped Porous Nanographenes Bearing a Tribenzotriquinacene Core by Three-fold Scholl Macrocyclization. Angewandte Chemie International Edition, 57(41), 13635-13639. doi:10.1002/anie.201808461
He, L., Ng, C. - F., Li, Y., Liu, Z., Kuck, D., and Chow, H. - F. (2018). Trefoil-Shaped Porous Nanographenes Bearing a Tribenzotriquinacene Core by Three-fold Scholl Macrocyclization. Angewandte Chemie International Edition 57, 13635-13639.
He, L., et al., 2018. Trefoil-Shaped Porous Nanographenes Bearing a Tribenzotriquinacene Core by Three-fold Scholl Macrocyclization. Angewandte Chemie International Edition, 57(41), p 13635-13639.
L. He, et al., “Trefoil-Shaped Porous Nanographenes Bearing a Tribenzotriquinacene Core by Three-fold Scholl Macrocyclization”, Angewandte Chemie International Edition, vol. 57, 2018, pp. 13635-13639.
He, L., Ng, C.-F., Li, Y., Liu, Z., Kuck, D., Chow, H.-F.: Trefoil-Shaped Porous Nanographenes Bearing a Tribenzotriquinacene Core by Three-fold Scholl Macrocyclization. Angewandte Chemie International Edition. 57, 13635-13639 (2018).
He, Lisi, Ng, Chun-Fai, Li, Yuke, Liu, Zhifeng, Kuck, Dietmar, and Chow, Hak-Fun. “Trefoil-Shaped Porous Nanographenes Bearing a Tribenzotriquinacene Core by Three-fold Scholl Macrocyclization”. Angewandte Chemie International Edition 57.41 (2018): 13635-13639.

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