The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)(2) and c-C6F10-1-(CF3)OH

Schaab J, Schwab M, Kratzert D, Schwabedissen J, Stammler H-G, Mitzel NW, Krossing I (2018)
CHEMICAL COMMUNICATIONS 54(67): 9294-9297.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The thermally unstable alpha-fluoroalcohol undecafluorocyclohexanol (c-C6F11OH) was prepared by addition of hydrogen fluoride to the corresponding ketone. c-C6F10(CF3) OH was obtained by protonation of its alkoxide [NMe4](+)[C7F13O](-). Decafluorocyclohexane-1,1-diol (c-C6F10(OH)(2)) was prepared by acidic workup of the corresponding alkoxide [NMe4](+)[C6F11O](-) with sulfuric acid, which yielded (c-C6F10(OH)(2)) and fluorosulfonic acid. The structures of c-C6F10(CF3)OH center dot 2H(2)O and of (c-C6F10(OH)(2)) were elucidated by single-crystal X-ray and gas-phase electron-diffraction studies.
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CHEMICAL COMMUNICATIONS
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54
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67
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9294-9297
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Schaab J, Schwab M, Kratzert D, et al. The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)(2) and c-C6F10-1-(CF3)OH. CHEMICAL COMMUNICATIONS. 2018;54(67):9294-9297.
Schaab, J., Schwab, M., Kratzert, D., Schwabedissen, J., Stammler, H. - G., Mitzel, N. W., & Krossing, I. (2018). The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)(2) and c-C6F10-1-(CF3)OH. CHEMICAL COMMUNICATIONS, 54(67), 9294-9297. doi:10.1039/c8cc05148h
Schaab, J., Schwab, M., Kratzert, D., Schwabedissen, J., Stammler, H. - G., Mitzel, N. W., and Krossing, I. (2018). The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)(2) and c-C6F10-1-(CF3)OH. CHEMICAL COMMUNICATIONS 54, 9294-9297.
Schaab, J., et al., 2018. The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)(2) and c-C6F10-1-(CF3)OH. CHEMICAL COMMUNICATIONS, 54(67), p 9294-9297.
J. Schaab, et al., “The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)(2) and c-C6F10-1-(CF3)OH”, CHEMICAL COMMUNICATIONS, vol. 54, 2018, pp. 9294-9297.
Schaab, J., Schwab, M., Kratzert, D., Schwabedissen, J., Stammler, H.-G., Mitzel, N.W., Krossing, I.: The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)(2) and c-C6F10-1-(CF3)OH. CHEMICAL COMMUNICATIONS. 54, 9294-9297 (2018).
Schaab, Jonas, Schwab, Miriam, Kratzert, Daniel, Schwabedissen, Jan, Stammler, Hans-Georg, Mitzel, Norbert W., and Krossing, Ingo. “The perfluorinated alcohols c-C6F11OH, c-C6F10-1,1-(OH)(2) and c-C6F10-1-(CF3)OH”. CHEMICAL COMMUNICATIONS 54.67 (2018): 9294-9297.

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