Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)(3)](-)

Kloesener J, Wiesemann M, Neumann B, Stammler H-G, Hoge B (2018)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018(35): 3971-3977.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
In this contribution the syntheses of transition metal complexes of the electron-withdrawing Sn(C2F5)(3) ligand are presented. The reaction of HSn(C2F5)(3) with organometallics LnM-R (M = Zn, W, Mo; R = Et, Me; L = CO, Cp), metal carbonyls [Ni(CO)(4)], and [{Fe(CO)(2)Cp}(2)], as well as chloro complexes such as [TiCl2Cp2], furnished the corresponding stannylated compounds. The electron-deficient Sn(C2F5)(3) ligand significantly influences the IR spectroscopic and structural features with respect to related non-fluorinated stannyl complexes.
Stichworte
Tin; Transition metals; Fluorinated ligands; Coordination modes
Erscheinungsjahr
2018
Zeitschriftentitel
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Band
2018
Ausgabe
35
Seite(n)
3971-3977
ISSN
1434-1948
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/2931497

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Kloesener J, Wiesemann M, Neumann B, Stammler H-G, Hoge B. Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)(3)](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2018;2018(35):3971-3977.
Kloesener, J., Wiesemann, M., Neumann, B., Stammler, H. - G., & Hoge, B. (2018). Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)(3)](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018(35), 3971-3977. doi:10.1002/ejic.201800796
Kloesener, J., Wiesemann, M., Neumann, B., Stammler, H. - G., and Hoge, B. (2018). Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)(3)](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018, 3971-3977.
Kloesener, J., et al., 2018. Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)(3)](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018(35), p 3971-3977.
J. Kloesener, et al., “Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)(3)](-)”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2018, 2018, pp. 3971-3977.
Kloesener, J., Wiesemann, M., Neumann, B., Stammler, H.-G., Hoge, B.: Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)(3)](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2018, 3971-3977 (2018).
Kloesener, Johannes, Wiesemann, Markus, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)(3)](-)”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018.35 (2018): 3971-3977.