2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry

Weber L (2018)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018(20-21): 2175-2227.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
2-Phosphaethynolates, particularly the sodium salts, Na(OCP), are exceedingly versatile nucleophiles, which renders these species important as precursors to phosphorus-containing -conjugated heterocycles. Moreover, the 2-phosphaethynolate anion serves as a potent phosphide transfer reagent giving rise to the first stable phosphinidine among other products. First studies also make evident that the phosphaethynolate ion serves as a fascinating ligand in coordination chemistry. Sodium salts of the long sought arsenic-containing analogue, 2-arsaethynolate, were synthesized only recently allowing the formation of arsenic-based element organics and coordination compounds.
Stichworte
Arsenic; Heterocycles; Phosphorus; Phosphaketenes; Phosphinidines
Erscheinungsjahr
2018
Zeitschriftentitel
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Band
2018
Ausgabe
20-21
Seite(n)
2175-2227
ISSN
1434-1948
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/2930527

Zitieren

Weber L. 2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2018;2018(20-21):2175-2227.
Weber, L. (2018). 2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018(20-21), 2175-2227. doi:10.1002/ejic.201800179
Weber, L. (2018). 2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018, 2175-2227.
Weber, L., 2018. 2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018(20-21), p 2175-2227.
L. Weber, “2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2018, 2018, pp. 2175-2227.
Weber, L.: 2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2018, 2175-2227 (2018).
Weber, Lothar. “2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018.20-21 (2018): 2175-2227.

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