Disulfuryl Dichloride ClSO2OSO2Cl: A Conformation and Polymorphism Chameleon

Betancourt AM, Schwabedissen J, Romano RM, Della Vedova CO, Beckers H, Willner H, Stammler H-G, Mitzel NW (2018)
CHEMISTRY-A EUROPEAN JOURNAL 24(41): 10409-10421.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor/in
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Abstract / Bemerkung
Disulfuryl dichloride ClSO2OSO2Cl was characterized by vibrational spectroscopy in the gaseous and liquid phase as well as in the Ar-matrix. By varying the temperature, certain bands could be assigned to several conformers. Gas-phase electron diffraction revealed a dominance of the anti-conformer at ambient temperature. The same conformation was found in the solid state. Via the in situ technique for crystallization, not less than four different modifications were identified. Among these different modifications, the structural parameters of the molecules remain relatively constant, but the aggregation pattern changes. Although the molecules aggregate by chlorineoxygen contacts in each modification, the geometrical parameters of these interaction show significant differences and were evaluated and are in part inconsistent with the halogen bonding concept.
Stichworte
disulfuryl dichloride; gas-phase electron diffraction; in situ; crystallization; matrix-isolation vibrational spectroscopy; solid-state; modifications
Erscheinungsjahr
2018
Zeitschriftentitel
CHEMISTRY-A EUROPEAN JOURNAL
Band
24
Ausgabe
41
Seite(n)
10409-10421
ISSN
0947-6539
eISSN
1521-3765
Page URI
https://pub.uni-bielefeld.de/record/2930513

Zitieren

Betancourt AM, Schwabedissen J, Romano RM, et al. Disulfuryl Dichloride ClSO2OSO2Cl: A Conformation and Polymorphism Chameleon. CHEMISTRY-A EUROPEAN JOURNAL. 2018;24(41):10409-10421.
Betancourt, A. M., Schwabedissen, J., Romano, R. M., Della Vedova, C. O., Beckers, H., Willner, H., Stammler, H. - G., et al. (2018). Disulfuryl Dichloride ClSO2OSO2Cl: A Conformation and Polymorphism Chameleon. CHEMISTRY-A EUROPEAN JOURNAL, 24(41), 10409-10421. doi:10.1002/chem.201800817
Betancourt, A. M., Schwabedissen, J., Romano, R. M., Della Vedova, C. O., Beckers, H., Willner, H., Stammler, H. - G., and Mitzel, N. W. (2018). Disulfuryl Dichloride ClSO2OSO2Cl: A Conformation and Polymorphism Chameleon. CHEMISTRY-A EUROPEAN JOURNAL 24, 10409-10421.
Betancourt, A.M., et al., 2018. Disulfuryl Dichloride ClSO2OSO2Cl: A Conformation and Polymorphism Chameleon. CHEMISTRY-A EUROPEAN JOURNAL, 24(41), p 10409-10421.
A.M. Betancourt, et al., “Disulfuryl Dichloride ClSO2OSO2Cl: A Conformation and Polymorphism Chameleon”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 24, 2018, pp. 10409-10421.
Betancourt, A.M., Schwabedissen, J., Romano, R.M., Della Vedova, C.O., Beckers, H., Willner, H., Stammler, H.-G., Mitzel, N.W.: Disulfuryl Dichloride ClSO2OSO2Cl: A Conformation and Polymorphism Chameleon. CHEMISTRY-A EUROPEAN JOURNAL. 24, 10409-10421 (2018).
Betancourt, Angelica Moreno, Schwabedissen, Jan, Romano, Rosana M., Della Vedova, Carlos O., Beckers, Helmut, Willner, Helge, Stammler, Hans-Georg, and Mitzel, Norbert W. “Disulfuryl Dichloride ClSO2OSO2Cl: A Conformation and Polymorphism Chameleon”. CHEMISTRY-A EUROPEAN JOURNAL 24.41 (2018): 10409-10421.

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