The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)(3){Sn(C2F5)(3)}](-) (X=Cl, Br, I, Sn(C2F5)(3))

Wiesemann M, Klösener J, Neumann B, Stammler H-G, Hoge B (2018)
CHEMISTRY-A EUROPEAN JOURNAL 24(17): 4336-4342.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
The tin-tin bond cleavage of hexaorganodistannanes by nucleophiles is a long-known reaction and widely used for stannate formation or stannyl group transfer. Herein, we detail our experiments to provide analytical evidence for the existence of the reasonably stable anionic complexes [XSn(C2F5)(3){Sn(C2F5)(3)}](-) (X=Cl, Br, I, Sn(C2F5)(3)) derived from hexakis(pentafluoroethyl)distannane. NMR investigations at low temperature lend further mechanistic insights. Thus, by detection of the imposing ion [Sn(C2F5)(3){Sn(C2F5)(3)}(2)](-), one can surmise that the chemistry of Sn-2(C2F5)(6) has more in common with the isolobal iodine than with classical distannanes.
Stichworte
distannanes; isolobal relationship; NMR spectroscopy; pseudohalides; tristannates
Erscheinungsjahr
2018
Zeitschriftentitel
CHEMISTRY-A EUROPEAN JOURNAL
Band
24
Ausgabe
17
Seite(n)
4336-4342
ISSN
0947-6539
eISSN
1521-3765
Page URI
https://pub.uni-bielefeld.de/record/2919305

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Wiesemann M, Klösener J, Neumann B, Stammler H-G, Hoge B. The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)(3){Sn(C2F5)(3)}](-) (X=Cl, Br, I, Sn(C2F5)(3)). CHEMISTRY-A EUROPEAN JOURNAL. 2018;24(17):4336-4342.
Wiesemann, M., Klösener, J., Neumann, B., Stammler, H. - G., & Hoge, B. (2018). The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)(3){Sn(C2F5)(3)}](-) (X=Cl, Br, I, Sn(C2F5)(3)). CHEMISTRY-A EUROPEAN JOURNAL, 24(17), 4336-4342. doi:10.1002/chem.201705069
Wiesemann, M., Klösener, J., Neumann, B., Stammler, H. - G., and Hoge, B. (2018). The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)(3){Sn(C2F5)(3)}](-) (X=Cl, Br, I, Sn(C2F5)(3)). CHEMISTRY-A EUROPEAN JOURNAL 24, 4336-4342.
Wiesemann, M., et al., 2018. The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)(3){Sn(C2F5)(3)}](-) (X=Cl, Br, I, Sn(C2F5)(3)). CHEMISTRY-A EUROPEAN JOURNAL, 24(17), p 4336-4342.
M. Wiesemann, et al., “The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)(3){Sn(C2F5)(3)}](-) (X=Cl, Br, I, Sn(C2F5)(3))”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 24, 2018, pp. 4336-4342.
Wiesemann, M., Klösener, J., Neumann, B., Stammler, H.-G., Hoge, B.: The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)(3){Sn(C2F5)(3)}](-) (X=Cl, Br, I, Sn(C2F5)(3)). CHEMISTRY-A EUROPEAN JOURNAL. 24, 4336-4342 (2018).
Wiesemann, Markus, Klösener, Johannes, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)(3){Sn(C2F5)(3)}](-) (X=Cl, Br, I, Sn(C2F5)(3))”. CHEMISTRY-A EUROPEAN JOURNAL 24.17 (2018): 4336-4342.

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