Diversity of aggregation motifs in gold(I) dithiocarboxylate complexes

Glatthor J, Neumann B, Stammler H-G, Mitzel NW (2018)
DALTON TRANSACTIONS 47(13): 4701-4706.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
Neutral, homoleptic gold(i) dithiocarboxylate complexes with different-sized Me, Pr-i, Mes, Tip, Mes* and Dmp substituents at the dithiocarboxylate unit were synthesized by reacting the corresponding dithiocarboxylic acid with potassium dicyanoaurate(i). They were characterized by IR spectroscopy and elemental analyses and their structures were determined by single crystal X-ray diffraction. The dinuclear complexes with an intramolecular d(10)-d(10) type aurophilic interaction aggregate through additional intermolecular aurophilic interactions in different binding motifs. The molecular structures and the patterns of aggregation in the solid state are presented and discussed with respect to the influence of the substituent size.
Erscheinungsjahr
2018
Zeitschriftentitel
DALTON TRANSACTIONS
Band
47
Ausgabe
13
Seite(n)
4701-4706
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/2919292

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Glatthor J, Neumann B, Stammler H-G, Mitzel NW. Diversity of aggregation motifs in gold(I) dithiocarboxylate complexes. DALTON TRANSACTIONS. 2018;47(13):4701-4706.
Glatthor, J., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2018). Diversity of aggregation motifs in gold(I) dithiocarboxylate complexes. DALTON TRANSACTIONS, 47(13), 4701-4706. doi:10.1039/c8dt00342d
Glatthor, J., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2018). Diversity of aggregation motifs in gold(I) dithiocarboxylate complexes. DALTON TRANSACTIONS 47, 4701-4706.
Glatthor, J., et al., 2018. Diversity of aggregation motifs in gold(I) dithiocarboxylate complexes. DALTON TRANSACTIONS, 47(13), p 4701-4706.
J. Glatthor, et al., “Diversity of aggregation motifs in gold(I) dithiocarboxylate complexes”, DALTON TRANSACTIONS, vol. 47, 2018, pp. 4701-4706.
Glatthor, J., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Diversity of aggregation motifs in gold(I) dithiocarboxylate complexes. DALTON TRANSACTIONS. 47, 4701-4706 (2018).
Glatthor, Johanna, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Diversity of aggregation motifs in gold(I) dithiocarboxylate complexes”. DALTON TRANSACTIONS 47.13 (2018): 4701-4706.

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