Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids
Alter C, Neumann B, Stammler H-G, Hoge B (2018)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018(7): 867-875.
Zeitschriftenaufsatz
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Einrichtung
Abstract / Bemerkung
Facile replacement of the p-fluorine atom in bis(diethylamino)pentafluorophenylphosphane [(Et2N)(2)PC6F5] by organolithium derivatives LiR (R = CH3, n-Bu, Ph), lithium alkoxides (R = OMe, OEt) and amides (NMe2, NEt2) is described. The obtained phosphanes p-R-C6F4-P(NEt2)(2) are fully characterized. Their acid-catalyzed hydrolysis affords the corresponding phosphinic acids p-R-C6F4-P(O)(H)OH, which are smoothly oxidized by treatment with a mixture of DMSO/I-2 to phosphonic acids p-R-C6F4-P(O)(OH)(2).
Stichworte
Phosphonic acid;
Phosphinic acid;
Phosphorus;
Fluorine;
Phosphanes
Erscheinungsjahr
2018
Zeitschriftentitel
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Band
2018
Ausgabe
7
Seite(n)
867-875
ISSN
1434-1948
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/2918661
Zitieren
Alter C, Neumann B, Stammler H-G, Hoge B. Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2018;2018(7):867-875.
Alter, C., Neumann, B., Stammler, H. - G., & Hoge, B. (2018). Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018(7), 867-875. doi:10.1002/ejic.201701402
Alter, Christian, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. 2018. “Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018 (7): 867-875.
Alter, C., Neumann, B., Stammler, H. - G., and Hoge, B. (2018). Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018, 867-875.
Alter, C., et al., 2018. Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018(7), p 867-875.
C. Alter, et al., “Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2018, 2018, pp. 867-875.
Alter, C., Neumann, B., Stammler, H.-G., Hoge, B.: Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2018, 867-875 (2018).
Alter, Christian, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018.7 (2018): 867-875.
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